[Benzyl(2-pyridylmeth­yl)amine]dichloridomercury(II)

The Hg atom in the title compound, [HgCl(2)(C(13)H(14)N(2))], adopts a distorted tetra­hedral geometry, being ligated by two N atoms of the benzyl(2-pyridylmeth­yl)amine (bpma) ligand and two Cl atoms. The dihedral angle between the least-squares planes through the chelate ring and Cl—Hg—Cl atoms is...

Descripción completa

Detalles Bibliográficos
Autores principales: Seo, Hoe-Joo, Kim, Young-Inn, Lee, You-Soon, Kang, Sung Kwon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967898/
https://www.ncbi.nlm.nih.gov/pubmed/21581525
http://dx.doi.org/10.1107/S1600536808040695
Descripción
Sumario:The Hg atom in the title compound, [HgCl(2)(C(13)H(14)N(2))], adopts a distorted tetra­hedral geometry, being ligated by two N atoms of the benzyl(2-pyridylmeth­yl)amine (bpma) ligand and two Cl atoms. The dihedral angle between the least-squares planes through the chelate ring and Cl—Hg—Cl atoms is 85.4 (1)°. The phenyl ring on the bpma ligand is twisted out of the pyridine plane, forming a dihedral angle of 76.0 (3)°. Disorder in this ring is also noted with two coplanar conformations having equal site occupancies.

Ejemplares similares