Chlorido{[2-(dicyclo­hexyl­phosphano­yl)eth­yl]bis­[2-(dicyclo­hexyl­phosphan­yl)eth­yl]phosphane}platinum(II) chloride dichloro­methane hemisolvate tetra­hydrate

The title compound, [PtCl(C(42)H(78)OP(4))]Cl·0.5CH(2)Cl(2)·4H(2)O, crystallizes as a contact ion-pair with two close inter­molecular C—H⋯Cl(−) contacts between CH acidic αH atoms of the phosphane ligand and the chloride anion. A chloride ligand together with three coordinating P ligand atoms create...

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Detalles Bibliográficos
Autores principales: Rieckborn, Timo Paul, Karakoc, Emine, He, Jin, Prosenc, Marc Heinrich
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967900/
https://www.ncbi.nlm.nih.gov/pubmed/21581527
http://dx.doi.org/10.1107/S1600536808041615
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author Rieckborn, Timo Paul
Karakoc, Emine
He, Jin
Prosenc, Marc Heinrich
author_facet Rieckborn, Timo Paul
Karakoc, Emine
He, Jin
Prosenc, Marc Heinrich
author_sort Rieckborn, Timo Paul
collection PubMed
description The title compound, [PtCl(C(42)H(78)OP(4))]Cl·0.5CH(2)Cl(2)·4H(2)O, crystallizes as a contact ion-pair with two close inter­molecular C—H⋯Cl(−) contacts between CH acidic αH atoms of the phosphane ligand and the chloride anion. A chloride ligand together with three coordinating P ligand atoms create a slightly distorted square-planar coordination environment around the Pt(II) center. An inter­molecular water O—H⋯Cl(−) and water O—H⋯OP hydrogen-bond network completes the coordination around the anion. In addition, a disordered CH(2)Cl(2) solvent mol­ecule cocrystallized within a hydro­phobic cavity spanned by the dicyclo­hexyl­phosphane ligands.
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spelling pubmed-29679002010-12-30 Chlorido{[2-(dicyclo­hexyl­phosphano­yl)eth­yl]bis­[2-(dicyclo­hexyl­phosphan­yl)eth­yl]phosphane}platinum(II) chloride dichloro­methane hemisolvate tetra­hydrate Rieckborn, Timo Paul Karakoc, Emine He, Jin Prosenc, Marc Heinrich Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PtCl(C(42)H(78)OP(4))]Cl·0.5CH(2)Cl(2)·4H(2)O, crystallizes as a contact ion-pair with two close inter­molecular C—H⋯Cl(−) contacts between CH acidic αH atoms of the phosphane ligand and the chloride anion. A chloride ligand together with three coordinating P ligand atoms create a slightly distorted square-planar coordination environment around the Pt(II) center. An inter­molecular water O—H⋯Cl(−) and water O—H⋯OP hydrogen-bond network completes the coordination around the anion. In addition, a disordered CH(2)Cl(2) solvent mol­ecule cocrystallized within a hydro­phobic cavity spanned by the dicyclo­hexyl­phosphane ligands. International Union of Crystallography 2008-12-13 /pmc/articles/PMC2967900/ /pubmed/21581527 http://dx.doi.org/10.1107/S1600536808041615 Text en © Rieckborn et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rieckborn, Timo Paul
Karakoc, Emine
He, Jin
Prosenc, Marc Heinrich
Chlorido{[2-(dicyclo­hexyl­phosphano­yl)eth­yl]bis­[2-(dicyclo­hexyl­phosphan­yl)eth­yl]phosphane}platinum(II) chloride dichloro­methane hemisolvate tetra­hydrate
title Chlorido{[2-(dicyclo­hexyl­phosphano­yl)eth­yl]bis­[2-(dicyclo­hexyl­phosphan­yl)eth­yl]phosphane}platinum(II) chloride dichloro­methane hemisolvate tetra­hydrate
title_full Chlorido{[2-(dicyclo­hexyl­phosphano­yl)eth­yl]bis­[2-(dicyclo­hexyl­phosphan­yl)eth­yl]phosphane}platinum(II) chloride dichloro­methane hemisolvate tetra­hydrate
title_fullStr Chlorido{[2-(dicyclo­hexyl­phosphano­yl)eth­yl]bis­[2-(dicyclo­hexyl­phosphan­yl)eth­yl]phosphane}platinum(II) chloride dichloro­methane hemisolvate tetra­hydrate
title_full_unstemmed Chlorido{[2-(dicyclo­hexyl­phosphano­yl)eth­yl]bis­[2-(dicyclo­hexyl­phosphan­yl)eth­yl]phosphane}platinum(II) chloride dichloro­methane hemisolvate tetra­hydrate
title_short Chlorido{[2-(dicyclo­hexyl­phosphano­yl)eth­yl]bis­[2-(dicyclo­hexyl­phosphan­yl)eth­yl]phosphane}platinum(II) chloride dichloro­methane hemisolvate tetra­hydrate
title_sort chlorido{[2-(dicyclo­hexyl­phosphano­yl)eth­yl]bis­[2-(dicyclo­hexyl­phosphan­yl)eth­yl]phosphane}platinum(ii) chloride dichloro­methane hemisolvate tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967900/
https://www.ncbi.nlm.nih.gov/pubmed/21581527
http://dx.doi.org/10.1107/S1600536808041615
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AT karakocemine chlorido2dicyclohexylphosphanoylethylbis2dicyclohexylphosphanylethylphosphaneplatinumiichloridedichloromethanehemisolvatetetrahydrate
AT hejin chlorido2dicyclohexylphosphanoylethylbis2dicyclohexylphosphanylethylphosphaneplatinumiichloridedichloromethanehemisolvatetetrahydrate
AT prosencmarcheinrich chlorido2dicyclohexylphosphanoylethylbis2dicyclohexylphosphanylethylphosphaneplatinumiichloridedichloromethanehemisolvatetetrahydrate

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