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Bis(μ-N-acetyl-N-phenylglycinato-κ(2) O:O′)bis[dinitrato-κ(4) O,O′-bis(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]
In the title complex, [La(2)(C(10)H(10)NO(3))(2)(NO(3))(4)(C(12)H(8)N(2))(4)], each La(III) ion is ten-coordinated by four N atoms from two bidentate 1,10-phenanthroline ligands and by six O atoms, two from the N-acetyl-N-phenylglycinate ligands and four from two nitrate anions. Two La(III) cations...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967901/ https://www.ncbi.nlm.nih.gov/pubmed/21581528 http://dx.doi.org/10.1107/S1600536808038075 |
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author | Gao, Xiaonan |
author_facet | Gao, Xiaonan |
author_sort | Gao, Xiaonan |
collection | PubMed |
description | In the title complex, [La(2)(C(10)H(10)NO(3))(2)(NO(3))(4)(C(12)H(8)N(2))(4)], each La(III) ion is ten-coordinated by four N atoms from two bidentate 1,10-phenanthroline ligands and by six O atoms, two from the N-acetyl-N-phenylglycinate ligands and four from two nitrate anions. Two La(III) cations, which exhibit a distorted bicapped square-antiprismatic coordination, are bridged by two N-acetyl-N-phenylglycinate ligands into a dimeric structure, generated by inversion symmetry. There is a π–π contact between the benzene rings [centroid–centroid distance = 3.409 (3) Å]. |
format | Text |
id | pubmed-2967901 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29679012010-12-30 Bis(μ-N-acetyl-N-phenylglycinato-κ(2) O:O′)bis[dinitrato-κ(4) O,O′-bis(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)] Gao, Xiaonan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [La(2)(C(10)H(10)NO(3))(2)(NO(3))(4)(C(12)H(8)N(2))(4)], each La(III) ion is ten-coordinated by four N atoms from two bidentate 1,10-phenanthroline ligands and by six O atoms, two from the N-acetyl-N-phenylglycinate ligands and four from two nitrate anions. Two La(III) cations, which exhibit a distorted bicapped square-antiprismatic coordination, are bridged by two N-acetyl-N-phenylglycinate ligands into a dimeric structure, generated by inversion symmetry. There is a π–π contact between the benzene rings [centroid–centroid distance = 3.409 (3) Å]. International Union of Crystallography 2008-12-13 /pmc/articles/PMC2967901/ /pubmed/21581528 http://dx.doi.org/10.1107/S1600536808038075 Text en © Xiao Nan Gao 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Xiaonan Bis(μ-N-acetyl-N-phenylglycinato-κ(2) O:O′)bis[dinitrato-κ(4) O,O′-bis(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)] |
title | Bis(μ-N-acetyl-N-phenylglycinato-κ(2)
O:O′)bis[dinitrato-κ(4)
O,O′-bis(1,10-phenanthroline-κ(2)
N,N′)lanthanum(III)] |
title_full | Bis(μ-N-acetyl-N-phenylglycinato-κ(2)
O:O′)bis[dinitrato-κ(4)
O,O′-bis(1,10-phenanthroline-κ(2)
N,N′)lanthanum(III)] |
title_fullStr | Bis(μ-N-acetyl-N-phenylglycinato-κ(2)
O:O′)bis[dinitrato-κ(4)
O,O′-bis(1,10-phenanthroline-κ(2)
N,N′)lanthanum(III)] |
title_full_unstemmed | Bis(μ-N-acetyl-N-phenylglycinato-κ(2)
O:O′)bis[dinitrato-κ(4)
O,O′-bis(1,10-phenanthroline-κ(2)
N,N′)lanthanum(III)] |
title_short | Bis(μ-N-acetyl-N-phenylglycinato-κ(2)
O:O′)bis[dinitrato-κ(4)
O,O′-bis(1,10-phenanthroline-κ(2)
N,N′)lanthanum(III)] |
title_sort | bis(μ-n-acetyl-n-phenylglycinato-κ(2)
o:o′)bis[dinitrato-κ(4)
o,o′-bis(1,10-phenanthroline-κ(2)
n,n′)lanthanum(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967901/ https://www.ncbi.nlm.nih.gov/pubmed/21581528 http://dx.doi.org/10.1107/S1600536808038075 |
work_keys_str_mv | AT gaoxiaonan bismnacetylnphenylglycinatok2oobisdinitratok4oobis110phenanthrolinek2nnlanthanumiii |