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Bis(μ-N-acetyl-N-phenyl­glycinato-κ(2) O:O′)bis­[dinitrato-κ(4) O,O′-bis­(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]

In the title complex, [La(2)(C(10)H(10)NO(3))(2)(NO(3))(4)(C(12)H(8)N(2))(4)], each La(III) ion is ten-coordinated by four N atoms from two bidentate 1,10-phenanthroline ligands and by six O atoms, two from the N-acetyl-N-phenyl­glycinate ligands and four from two nitrate anions. Two La(III) cations...

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Detalles Bibliográficos
Autor principal: Gao, Xiaonan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967901/
https://www.ncbi.nlm.nih.gov/pubmed/21581528
http://dx.doi.org/10.1107/S1600536808038075
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author Gao, Xiaonan
author_facet Gao, Xiaonan
author_sort Gao, Xiaonan
collection PubMed
description In the title complex, [La(2)(C(10)H(10)NO(3))(2)(NO(3))(4)(C(12)H(8)N(2))(4)], each La(III) ion is ten-coordinated by four N atoms from two bidentate 1,10-phenanthroline ligands and by six O atoms, two from the N-acetyl-N-phenyl­glycinate ligands and four from two nitrate anions. Two La(III) cations, which exhibit a distorted bicapped square-anti­prismatic coordination, are bridged by two N-acetyl-N-phenyl­glycinate ligands into a dimeric structure, generated by inversion symmetry. There is a π–π contact between the benzene rings [centroid–centroid distance = 3.409 (3) Å].
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spelling pubmed-29679012010-12-30 Bis(μ-N-acetyl-N-phenyl­glycinato-κ(2) O:O′)bis­[dinitrato-κ(4) O,O′-bis­(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)] Gao, Xiaonan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [La(2)(C(10)H(10)NO(3))(2)(NO(3))(4)(C(12)H(8)N(2))(4)], each La(III) ion is ten-coordinated by four N atoms from two bidentate 1,10-phenanthroline ligands and by six O atoms, two from the N-acetyl-N-phenyl­glycinate ligands and four from two nitrate anions. Two La(III) cations, which exhibit a distorted bicapped square-anti­prismatic coordination, are bridged by two N-acetyl-N-phenyl­glycinate ligands into a dimeric structure, generated by inversion symmetry. There is a π–π contact between the benzene rings [centroid–centroid distance = 3.409 (3) Å]. International Union of Crystallography 2008-12-13 /pmc/articles/PMC2967901/ /pubmed/21581528 http://dx.doi.org/10.1107/S1600536808038075 Text en © Xiao Nan Gao 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Xiaonan
Bis(μ-N-acetyl-N-phenyl­glycinato-κ(2) O:O′)bis­[dinitrato-κ(4) O,O′-bis­(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]
title Bis(μ-N-acetyl-N-phenyl­glycinato-κ(2) O:O′)bis­[dinitrato-κ(4) O,O′-bis­(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]
title_full Bis(μ-N-acetyl-N-phenyl­glycinato-κ(2) O:O′)bis­[dinitrato-κ(4) O,O′-bis­(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]
title_fullStr Bis(μ-N-acetyl-N-phenyl­glycinato-κ(2) O:O′)bis­[dinitrato-κ(4) O,O′-bis­(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]
title_full_unstemmed Bis(μ-N-acetyl-N-phenyl­glycinato-κ(2) O:O′)bis­[dinitrato-κ(4) O,O′-bis­(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]
title_short Bis(μ-N-acetyl-N-phenyl­glycinato-κ(2) O:O′)bis­[dinitrato-κ(4) O,O′-bis­(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]
title_sort bis(μ-n-acetyl-n-phenyl­glycinato-κ(2) o:o′)bis­[dinitrato-κ(4) o,o′-bis­(1,10-phenanthroline-κ(2) n,n′)lanthanum(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967901/
https://www.ncbi.nlm.nih.gov/pubmed/21581528
http://dx.doi.org/10.1107/S1600536808038075
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