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(4-Hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3) O (2),N (1),S)(1,10-phenanthroline-κ(2) N,N′)zinc(II) dimethyl sulfoxide disolvate monohydrate
The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(12)H(8)N(2))]·2C(2)H(6)OS·H(2)O, is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a distorted square-pyramidal enviroment. Hydrogen bonds link the mononuclear molecule, the water and the dimet...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967903/ https://www.ncbi.nlm.nih.gov/pubmed/21581531 http://dx.doi.org/10.1107/S160053680804169X |
| _version_ | 1782189722425098240 |
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| author | Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng |
| author_facet | Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng |
| author_sort | Tan, Kong Wai |
| collection | PubMed |
| description | The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(12)H(8)N(2))]·2C(2)H(6)OS·H(2)O, is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a distorted square-pyramidal enviroment. Hydrogen bonds link the mononuclear molecule, the water and the dimethyl sulfoxide (DMSO) molecules into a linear chain motif. One DMSO molecule is disordered over two positions in respect of the S atom in an approximate 1:1 ratio. |
| format | Text |
| id | pubmed-2967903 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29679032010-12-30 (4-Hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3) O (2),N (1),S)(1,10-phenanthroline-κ(2) N,N′)zinc(II) dimethyl sulfoxide disolvate monohydrate Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(12)H(8)N(2))]·2C(2)H(6)OS·H(2)O, is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a distorted square-pyramidal enviroment. Hydrogen bonds link the mononuclear molecule, the water and the dimethyl sulfoxide (DMSO) molecules into a linear chain motif. One DMSO molecule is disordered over two positions in respect of the S atom in an approximate 1:1 ratio. International Union of Crystallography 2008-12-13 /pmc/articles/PMC2967903/ /pubmed/21581531 http://dx.doi.org/10.1107/S160053680804169X Text en © Tan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng (4-Hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3) O (2),N (1),S)(1,10-phenanthroline-κ(2) N,N′)zinc(II) dimethyl sulfoxide disolvate monohydrate |
| title | (4-Hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
O
(2),N
(1),S)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) dimethyl sulfoxide disolvate monohydrate |
| title_full | (4-Hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
O
(2),N
(1),S)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) dimethyl sulfoxide disolvate monohydrate |
| title_fullStr | (4-Hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
O
(2),N
(1),S)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) dimethyl sulfoxide disolvate monohydrate |
| title_full_unstemmed | (4-Hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
O
(2),N
(1),S)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) dimethyl sulfoxide disolvate monohydrate |
| title_short | (4-Hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
O
(2),N
(1),S)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) dimethyl sulfoxide disolvate monohydrate |
| title_sort | (4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-κ(3)
o
(2),n
(1),s)(1,10-phenanthroline-κ(2)
n,n′)zinc(ii) dimethyl sulfoxide disolvate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967903/ https://www.ncbi.nlm.nih.gov/pubmed/21581531 http://dx.doi.org/10.1107/S160053680804169X |
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