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Aqua(dicyanamido-κN (1))(nitrato-κ(2) O,O′)(2,3,5,6-tetra-2-pyridylpyrazine-κ(3) N (2),N (1),N (6))manganese(II)
In the title compound, [Mn(C(2)N(3))(NO(3))(C(24)H(16)N(6))(H(2)O)], the central manganese(II) ion is heptacoordinated to a tridentate 2,3,5,6-tetra-2-pyridylpyrazine ligand (tppz), a bidentate nitrate ligand, a terminal monodentate dicyanamide ligand (dca) and a water molecule. The structure cont...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967907/ https://www.ncbi.nlm.nih.gov/pubmed/21581535 http://dx.doi.org/10.1107/S1600536808041755 |
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author | Callejo, Lorena De la Pinta, Noelia Vitoria, Pablo Cortés, Roberto |
author_facet | Callejo, Lorena De la Pinta, Noelia Vitoria, Pablo Cortés, Roberto |
author_sort | Callejo, Lorena |
collection | PubMed |
description | In the title compound, [Mn(C(2)N(3))(NO(3))(C(24)H(16)N(6))(H(2)O)], the central manganese(II) ion is heptacoordinated to a tridentate 2,3,5,6-tetra-2-pyridylpyrazine ligand (tppz), a bidentate nitrate ligand, a terminal monodentate dicyanamide ligand (dca) and a water molecule. The structure contains isolated neutral complexes, which are linked by O(water)—H⋯N hydrogen bonds generating chains along [010]. |
format | Text |
id | pubmed-2967907 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29679072010-12-30 Aqua(dicyanamido-κN (1))(nitrato-κ(2) O,O′)(2,3,5,6-tetra-2-pyridylpyrazine-κ(3) N (2),N (1),N (6))manganese(II) Callejo, Lorena De la Pinta, Noelia Vitoria, Pablo Cortés, Roberto Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(2)N(3))(NO(3))(C(24)H(16)N(6))(H(2)O)], the central manganese(II) ion is heptacoordinated to a tridentate 2,3,5,6-tetra-2-pyridylpyrazine ligand (tppz), a bidentate nitrate ligand, a terminal monodentate dicyanamide ligand (dca) and a water molecule. The structure contains isolated neutral complexes, which are linked by O(water)—H⋯N hydrogen bonds generating chains along [010]. International Union of Crystallography 2008-12-13 /pmc/articles/PMC2967907/ /pubmed/21581535 http://dx.doi.org/10.1107/S1600536808041755 Text en © Callejo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Callejo, Lorena De la Pinta, Noelia Vitoria, Pablo Cortés, Roberto Aqua(dicyanamido-κN (1))(nitrato-κ(2) O,O′)(2,3,5,6-tetra-2-pyridylpyrazine-κ(3) N (2),N (1),N (6))manganese(II) |
title | Aqua(dicyanamido-κN
(1))(nitrato-κ(2)
O,O′)(2,3,5,6-tetra-2-pyridylpyrazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) |
title_full | Aqua(dicyanamido-κN
(1))(nitrato-κ(2)
O,O′)(2,3,5,6-tetra-2-pyridylpyrazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) |
title_fullStr | Aqua(dicyanamido-κN
(1))(nitrato-κ(2)
O,O′)(2,3,5,6-tetra-2-pyridylpyrazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) |
title_full_unstemmed | Aqua(dicyanamido-κN
(1))(nitrato-κ(2)
O,O′)(2,3,5,6-tetra-2-pyridylpyrazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) |
title_short | Aqua(dicyanamido-κN
(1))(nitrato-κ(2)
O,O′)(2,3,5,6-tetra-2-pyridylpyrazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) |
title_sort | aqua(dicyanamido-κn
(1))(nitrato-κ(2)
o,o′)(2,3,5,6-tetra-2-pyridylpyrazine-κ(3)
n
(2),n
(1),n
(6))manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967907/ https://www.ncbi.nlm.nih.gov/pubmed/21581535 http://dx.doi.org/10.1107/S1600536808041755 |
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