catena-Poly[[[N,N′-bis­(3-methoxy­benzyl­idene)ethyl­enediamine]copper(I)]-μ-thio­cyanato-κ(2) N:S]

In the cyrstal structure of the title compound, [Cu(NCS)(C(18)H(20)N(2)O(2))](n), the Cu(I) atom is coordinated in a distorted tetra­hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio­cyanate anions. The thio­cyanate anion brid...

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Detalles Bibliográficos
Autores principales: Khalaji, Aliakbar Dehno, Hadadzadeh, Hassan, Gotoh, Kazuma, Ishida, Hiroyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967908/
https://www.ncbi.nlm.nih.gov/pubmed/21581537
http://dx.doi.org/10.1107/S1600536808041925
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author Khalaji, Aliakbar Dehno
Hadadzadeh, Hassan
Gotoh, Kazuma
Ishida, Hiroyuki
author_facet Khalaji, Aliakbar Dehno
Hadadzadeh, Hassan
Gotoh, Kazuma
Ishida, Hiroyuki
author_sort Khalaji, Aliakbar Dehno
collection PubMed
description In the cyrstal structure of the title compound, [Cu(NCS)(C(18)H(20)N(2)O(2))](n), the Cu(I) atom is coordinated in a distorted tetra­hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio­cyanate anions. The thio­cyanate anion bridges the Cu(I) atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.
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spelling pubmed-29679082010-12-30 catena-Poly[[[N,N′-bis­(3-methoxy­benzyl­idene)ethyl­enediamine]copper(I)]-μ-thio­cyanato-κ(2) N:S] Khalaji, Aliakbar Dehno Hadadzadeh, Hassan Gotoh, Kazuma Ishida, Hiroyuki Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cyrstal structure of the title compound, [Cu(NCS)(C(18)H(20)N(2)O(2))](n), the Cu(I) atom is coordinated in a distorted tetra­hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio­cyanate anions. The thio­cyanate anion bridges the Cu(I) atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°. International Union of Crystallography 2008-12-13 /pmc/articles/PMC2967908/ /pubmed/21581537 http://dx.doi.org/10.1107/S1600536808041925 Text en © Khalaji et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khalaji, Aliakbar Dehno
Hadadzadeh, Hassan
Gotoh, Kazuma
Ishida, Hiroyuki
catena-Poly[[[N,N′-bis­(3-methoxy­benzyl­idene)ethyl­enediamine]copper(I)]-μ-thio­cyanato-κ(2) N:S]
title catena-Poly[[[N,N′-bis­(3-methoxy­benzyl­idene)ethyl­enediamine]copper(I)]-μ-thio­cyanato-κ(2) N:S]
title_full catena-Poly[[[N,N′-bis­(3-methoxy­benzyl­idene)ethyl­enediamine]copper(I)]-μ-thio­cyanato-κ(2) N:S]
title_fullStr catena-Poly[[[N,N′-bis­(3-methoxy­benzyl­idene)ethyl­enediamine]copper(I)]-μ-thio­cyanato-κ(2) N:S]
title_full_unstemmed catena-Poly[[[N,N′-bis­(3-methoxy­benzyl­idene)ethyl­enediamine]copper(I)]-μ-thio­cyanato-κ(2) N:S]
title_short catena-Poly[[[N,N′-bis­(3-methoxy­benzyl­idene)ethyl­enediamine]copper(I)]-μ-thio­cyanato-κ(2) N:S]
title_sort catena-poly[[[n,n′-bis­(3-methoxy­benzyl­idene)ethyl­enediamine]copper(i)]-μ-thio­cyanato-κ(2) n:s]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967908/
https://www.ncbi.nlm.nih.gov/pubmed/21581537
http://dx.doi.org/10.1107/S1600536808041925
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