[8-(Diphenyl­phosphan­yl)naphthyl-κ(2) C (1),P](phenyl­ethyn­yl)tris­(trimethyl­phosphane-κP)iron(II)

The title compound, [Fe(C(8)H(5))(C(22)H(16)P)(C(3)H(9)P)(3)], was synthesized by the addition of phenyl­ethine to a solution of the parent methyl iron complex Fe(CH(3)){P(C(6)H(5))(2)(C(10)H(6))}(PMe(3))(3) at 213 K, accompanied by evolution of methane. The coordination around the iron center can b...

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Detalles Bibliográficos
Autores principales: Beck, Robert, Sun, Hongjian, Guan, Dexin, Li, Xiaoyan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967909/
https://www.ncbi.nlm.nih.gov/pubmed/21581538
http://dx.doi.org/10.1107/S1600536808041421
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author Beck, Robert
Sun, Hongjian
Guan, Dexin
Li, Xiaoyan
author_facet Beck, Robert
Sun, Hongjian
Guan, Dexin
Li, Xiaoyan
author_sort Beck, Robert
collection PubMed
description The title compound, [Fe(C(8)H(5))(C(22)H(16)P)(C(3)H(9)P)(3)], was synthesized by the addition of phenyl­ethine to a solution of the parent methyl iron complex Fe(CH(3)){P(C(6)H(5))(2)(C(10)H(6))}(PMe(3))(3) at 213 K, accompanied by evolution of methane. The coordination around the iron center can be described as slightly distorted octa­hedral [Fe—P 2.2485 (12)–2.2902 (12) Å; Fe—C 1.918 (5), 2.015 (4) Å], with a meridional arrangement of the trimethyl­phosphine ligands and the introduced terminal alkinyl-ligand trans to the P(Ph)(2)-anchoring group.
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spelling pubmed-29679092010-12-30 [8-(Diphenyl­phosphan­yl)naphthyl-κ(2) C (1),P](phenyl­ethyn­yl)tris­(trimethyl­phosphane-κP)iron(II) Beck, Robert Sun, Hongjian Guan, Dexin Li, Xiaoyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(8)H(5))(C(22)H(16)P)(C(3)H(9)P)(3)], was synthesized by the addition of phenyl­ethine to a solution of the parent methyl iron complex Fe(CH(3)){P(C(6)H(5))(2)(C(10)H(6))}(PMe(3))(3) at 213 K, accompanied by evolution of methane. The coordination around the iron center can be described as slightly distorted octa­hedral [Fe—P 2.2485 (12)–2.2902 (12) Å; Fe—C 1.918 (5), 2.015 (4) Å], with a meridional arrangement of the trimethyl­phosphine ligands and the introduced terminal alkinyl-ligand trans to the P(Ph)(2)-anchoring group. International Union of Crystallography 2008-12-13 /pmc/articles/PMC2967909/ /pubmed/21581538 http://dx.doi.org/10.1107/S1600536808041421 Text en © Beck et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Beck, Robert
Sun, Hongjian
Guan, Dexin
Li, Xiaoyan
[8-(Diphenyl­phosphan­yl)naphthyl-κ(2) C (1),P](phenyl­ethyn­yl)tris­(trimethyl­phosphane-κP)iron(II)
title [8-(Diphenyl­phosphan­yl)naphthyl-κ(2) C (1),P](phenyl­ethyn­yl)tris­(trimethyl­phosphane-κP)iron(II)
title_full [8-(Diphenyl­phosphan­yl)naphthyl-κ(2) C (1),P](phenyl­ethyn­yl)tris­(trimethyl­phosphane-κP)iron(II)
title_fullStr [8-(Diphenyl­phosphan­yl)naphthyl-κ(2) C (1),P](phenyl­ethyn­yl)tris­(trimethyl­phosphane-κP)iron(II)
title_full_unstemmed [8-(Diphenyl­phosphan­yl)naphthyl-κ(2) C (1),P](phenyl­ethyn­yl)tris­(trimethyl­phosphane-κP)iron(II)
title_short [8-(Diphenyl­phosphan­yl)naphthyl-κ(2) C (1),P](phenyl­ethyn­yl)tris­(trimethyl­phosphane-κP)iron(II)
title_sort [8-(diphenyl­phosphan­yl)naphthyl-κ(2) c (1),p](phenyl­ethyn­yl)tris­(trimethyl­phosphane-κp)iron(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967909/
https://www.ncbi.nlm.nih.gov/pubmed/21581538
http://dx.doi.org/10.1107/S1600536808041421
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AT guandexin 8diphenylphosphanylnaphthylk2c1pphenylethynyltristrimethylphosphanekpironii
AT lixiaoyan 8diphenylphosphanylnaphthylk2c1pphenylethynyltristrimethylphosphanekpironii

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