1,3-Di-1-adamantylimidazolium (phthalocyaninato)lithium(I) acetone hemisolvate monohydrate

The asymmetric unit of the title compound, (C(23)H(33)N(2))[Li(C(32)H(16)N(8))]·0.5C(3)H(6)O·H(2)O, consists of two symmetry-unrelated lithium phthalocyanine (LiPc(−)) half-anions, centered at (1,0,0) and (0,[Image: see text],0), respectively, the bis­(adamant­yl)imidazolium cation (BAI(+)), occupying a general site, an acetone mol­ecule, disordered about the inversion centre at (0, [Image: see text], [Image: see text]) and a water mol­ecule at a general site. The LiPc(−) anions pack in a stepped pattern enclosing the bis­(adamant­yl)imidazolium cation. Attractions between the anion and cation are mediated by a water mol­ecule which forms O—H⋯N hydrogen bonds. In addition, two C—H⋯O interactions are seen.