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Poly[diaqua-μ-oxalato-μ-pyrazine-2-carbox­yl­ato-lanthanum(III)]

In the title complex, [La(C(5)H(3)N(2)O(2))(C(2)O(4))(H(2)O)(2)](n), the La(III) ion is coordinated by one N and three O atoms from two pyrazine-2-carboxylate ligands, by four O atoms from two oxalate ligands and by two O atoms of two water molecules, displaying a distorted bicapped square-anti­pris...

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Detalles Bibliográficos
Autores principales: Han, Lu, Meng, Qun-Hui, Hao, Jian-Dong, Luo, Yi-Fan, Zeng, Rong-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967913/
https://www.ncbi.nlm.nih.gov/pubmed/21581542
http://dx.doi.org/10.1107/S1600536808041664
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author Han, Lu
Meng, Qun-Hui
Hao, Jian-Dong
Luo, Yi-Fan
Zeng, Rong-Hua
author_facet Han, Lu
Meng, Qun-Hui
Hao, Jian-Dong
Luo, Yi-Fan
Zeng, Rong-Hua
author_sort Han, Lu
collection PubMed
description In the title complex, [La(C(5)H(3)N(2)O(2))(C(2)O(4))(H(2)O)(2)](n), the La(III) ion is coordinated by one N and three O atoms from two pyrazine-2-carboxylate ligands, by four O atoms from two oxalate ligands and by two O atoms of two water molecules, displaying a distorted bicapped square-anti­prismatic geometry. The carboxyl­ate groups of pyrazine-2-carboxyl­ate and oxalate ligands link the lanthanum metal centres, forming layers parallel to (10[Image: see text]). The layers are further connected by inter­molecular O—H⋯O and N—H⋯O hydrogen-bonding inter­actions, forming a three-dimensional supra­molecular network.
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spelling pubmed-29679132010-12-30 Poly[diaqua-μ-oxalato-μ-pyrazine-2-carbox­yl­ato-lanthanum(III)] Han, Lu Meng, Qun-Hui Hao, Jian-Dong Luo, Yi-Fan Zeng, Rong-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [La(C(5)H(3)N(2)O(2))(C(2)O(4))(H(2)O)(2)](n), the La(III) ion is coordinated by one N and three O atoms from two pyrazine-2-carboxylate ligands, by four O atoms from two oxalate ligands and by two O atoms of two water molecules, displaying a distorted bicapped square-anti­prismatic geometry. The carboxyl­ate groups of pyrazine-2-carboxyl­ate and oxalate ligands link the lanthanum metal centres, forming layers parallel to (10[Image: see text]). The layers are further connected by inter­molecular O—H⋯O and N—H⋯O hydrogen-bonding inter­actions, forming a three-dimensional supra­molecular network. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967913/ /pubmed/21581542 http://dx.doi.org/10.1107/S1600536808041664 Text en © Han et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Han, Lu
Meng, Qun-Hui
Hao, Jian-Dong
Luo, Yi-Fan
Zeng, Rong-Hua
Poly[diaqua-μ-oxalato-μ-pyrazine-2-carbox­yl­ato-lanthanum(III)]
title Poly[diaqua-μ-oxalato-μ-pyrazine-2-carbox­yl­ato-lanthanum(III)]
title_full Poly[diaqua-μ-oxalato-μ-pyrazine-2-carbox­yl­ato-lanthanum(III)]
title_fullStr Poly[diaqua-μ-oxalato-μ-pyrazine-2-carbox­yl­ato-lanthanum(III)]
title_full_unstemmed Poly[diaqua-μ-oxalato-μ-pyrazine-2-carbox­yl­ato-lanthanum(III)]
title_short Poly[diaqua-μ-oxalato-μ-pyrazine-2-carbox­yl­ato-lanthanum(III)]
title_sort poly[diaqua-μ-oxalato-μ-pyrazine-2-carbox­yl­ato-lanthanum(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967913/
https://www.ncbi.nlm.nih.gov/pubmed/21581542
http://dx.doi.org/10.1107/S1600536808041664
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