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Poly[diaqua-μ-oxalato-μ-pyrazine-2-carboxylato-lanthanum(III)]
In the title complex, [La(C(5)H(3)N(2)O(2))(C(2)O(4))(H(2)O)(2)](n), the La(III) ion is coordinated by one N and three O atoms from two pyrazine-2-carboxylate ligands, by four O atoms from two oxalate ligands and by two O atoms of two water molecules, displaying a distorted bicapped square-antipris...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967913/ https://www.ncbi.nlm.nih.gov/pubmed/21581542 http://dx.doi.org/10.1107/S1600536808041664 |
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author | Han, Lu Meng, Qun-Hui Hao, Jian-Dong Luo, Yi-Fan Zeng, Rong-Hua |
author_facet | Han, Lu Meng, Qun-Hui Hao, Jian-Dong Luo, Yi-Fan Zeng, Rong-Hua |
author_sort | Han, Lu |
collection | PubMed |
description | In the title complex, [La(C(5)H(3)N(2)O(2))(C(2)O(4))(H(2)O)(2)](n), the La(III) ion is coordinated by one N and three O atoms from two pyrazine-2-carboxylate ligands, by four O atoms from two oxalate ligands and by two O atoms of two water molecules, displaying a distorted bicapped square-antiprismatic geometry. The carboxylate groups of pyrazine-2-carboxylate and oxalate ligands link the lanthanum metal centres, forming layers parallel to (10[Image: see text]). The layers are further connected by intermolecular O—H⋯O and N—H⋯O hydrogen-bonding interactions, forming a three-dimensional supramolecular network. |
format | Text |
id | pubmed-2967913 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29679132010-12-30 Poly[diaqua-μ-oxalato-μ-pyrazine-2-carboxylato-lanthanum(III)] Han, Lu Meng, Qun-Hui Hao, Jian-Dong Luo, Yi-Fan Zeng, Rong-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [La(C(5)H(3)N(2)O(2))(C(2)O(4))(H(2)O)(2)](n), the La(III) ion is coordinated by one N and three O atoms from two pyrazine-2-carboxylate ligands, by four O atoms from two oxalate ligands and by two O atoms of two water molecules, displaying a distorted bicapped square-antiprismatic geometry. The carboxylate groups of pyrazine-2-carboxylate and oxalate ligands link the lanthanum metal centres, forming layers parallel to (10[Image: see text]). The layers are further connected by intermolecular O—H⋯O and N—H⋯O hydrogen-bonding interactions, forming a three-dimensional supramolecular network. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967913/ /pubmed/21581542 http://dx.doi.org/10.1107/S1600536808041664 Text en © Han et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Han, Lu Meng, Qun-Hui Hao, Jian-Dong Luo, Yi-Fan Zeng, Rong-Hua Poly[diaqua-μ-oxalato-μ-pyrazine-2-carboxylato-lanthanum(III)] |
title | Poly[diaqua-μ-oxalato-μ-pyrazine-2-carboxylato-lanthanum(III)] |
title_full | Poly[diaqua-μ-oxalato-μ-pyrazine-2-carboxylato-lanthanum(III)] |
title_fullStr | Poly[diaqua-μ-oxalato-μ-pyrazine-2-carboxylato-lanthanum(III)] |
title_full_unstemmed | Poly[diaqua-μ-oxalato-μ-pyrazine-2-carboxylato-lanthanum(III)] |
title_short | Poly[diaqua-μ-oxalato-μ-pyrazine-2-carboxylato-lanthanum(III)] |
title_sort | poly[diaqua-μ-oxalato-μ-pyrazine-2-carboxylato-lanthanum(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967913/ https://www.ncbi.nlm.nih.gov/pubmed/21581542 http://dx.doi.org/10.1107/S1600536808041664 |
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