Bis(triethyl­ammonium) bis­(μ-pyrazine-2,3-dithiol­ato)bis­(pyrazine-2,3-dithio­lato)diferrate(III) methanol disolvate

In the title compound, (C(6)H(16)N)(2)[Fe(2)(C(4)H(2)N(2)S(2))(4)]·2CH(4)O, the [Fe(III)(pdt)(2)](−) anion (pdt is pyrazine-2,3-dithiol­ate) forms a centrosymmetric dimer supported by two Fe(III)—S bonds [Fe—S = 2.4787 (4) Å]. In the crystal structure, dimers form a one-dimensional stack along the b...

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Detalles Bibliográficos
Autores principales: Yamaguchi, Toshiki, Masaoka, Shigeyuki, Sakai, Ken
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967914/
https://www.ncbi.nlm.nih.gov/pubmed/21581543
http://dx.doi.org/10.1107/S1600536808041949
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author Yamaguchi, Toshiki
Masaoka, Shigeyuki
Sakai, Ken
author_facet Yamaguchi, Toshiki
Masaoka, Shigeyuki
Sakai, Ken
author_sort Yamaguchi, Toshiki
collection PubMed
description In the title compound, (C(6)H(16)N)(2)[Fe(2)(C(4)H(2)N(2)S(2))(4)]·2CH(4)O, the [Fe(III)(pdt)(2)](−) anion (pdt is pyrazine-2,3-dithiol­ate) forms a centrosymmetric dimer supported by two Fe(III)—S bonds [Fe—S = 2.4787 (4) Å]. In the crystal structure, dimers form a one-dimensional stack along the b axis via π–π stacking inter­actions, the inter­planar separation between adjacent dimers being 3.51 (2) Å. The methanol solvent mol­ecule is involved in two hydrogen bonds in which the hydroxyl group acts as a hydrogen-bond donor to the N atom of a pdt ligand and the O atom acts as an acceptor for the NH group of the triethyl­ammonium cation.
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spelling pubmed-29679142010-12-30 Bis(triethyl­ammonium) bis­(μ-pyrazine-2,3-dithiol­ato)bis­(pyrazine-2,3-dithio­lato)diferrate(III) methanol disolvate Yamaguchi, Toshiki Masaoka, Shigeyuki Sakai, Ken Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(6)H(16)N)(2)[Fe(2)(C(4)H(2)N(2)S(2))(4)]·2CH(4)O, the [Fe(III)(pdt)(2)](−) anion (pdt is pyrazine-2,3-dithiol­ate) forms a centrosymmetric dimer supported by two Fe(III)—S bonds [Fe—S = 2.4787 (4) Å]. In the crystal structure, dimers form a one-dimensional stack along the b axis via π–π stacking inter­actions, the inter­planar separation between adjacent dimers being 3.51 (2) Å. The methanol solvent mol­ecule is involved in two hydrogen bonds in which the hydroxyl group acts as a hydrogen-bond donor to the N atom of a pdt ligand and the O atom acts as an acceptor for the NH group of the triethyl­ammonium cation. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967914/ /pubmed/21581543 http://dx.doi.org/10.1107/S1600536808041949 Text en © Yamaguchi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yamaguchi, Toshiki
Masaoka, Shigeyuki
Sakai, Ken
Bis(triethyl­ammonium) bis­(μ-pyrazine-2,3-dithiol­ato)bis­(pyrazine-2,3-dithio­lato)diferrate(III) methanol disolvate
title Bis(triethyl­ammonium) bis­(μ-pyrazine-2,3-dithiol­ato)bis­(pyrazine-2,3-dithio­lato)diferrate(III) methanol disolvate
title_full Bis(triethyl­ammonium) bis­(μ-pyrazine-2,3-dithiol­ato)bis­(pyrazine-2,3-dithio­lato)diferrate(III) methanol disolvate
title_fullStr Bis(triethyl­ammonium) bis­(μ-pyrazine-2,3-dithiol­ato)bis­(pyrazine-2,3-dithio­lato)diferrate(III) methanol disolvate
title_full_unstemmed Bis(triethyl­ammonium) bis­(μ-pyrazine-2,3-dithiol­ato)bis­(pyrazine-2,3-dithio­lato)diferrate(III) methanol disolvate
title_short Bis(triethyl­ammonium) bis­(μ-pyrazine-2,3-dithiol­ato)bis­(pyrazine-2,3-dithio­lato)diferrate(III) methanol disolvate
title_sort bis(triethyl­ammonium) bis­(μ-pyrazine-2,3-dithiol­ato)bis­(pyrazine-2,3-dithio­lato)diferrate(iii) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967914/
https://www.ncbi.nlm.nih.gov/pubmed/21581543
http://dx.doi.org/10.1107/S1600536808041949
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AT masaokashigeyuki bistriethylammoniumbismpyrazine23dithiolatobispyrazine23dithiolatodiferrateiiimethanoldisolvate
AT sakaiken bistriethylammoniumbismpyrazine23dithiolatobispyrazine23dithiolatodiferrateiiimethanoldisolvate

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