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Bis(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitro-2-oxidobenzoato-κ(2) O (1),O (2))cobalt(II)
In the title compound, [Co(C(7)H(2)N(2)O(7))(C(10)H(8)N(2))(2)], the Co(II) atom is coordinated by four N atoms from two 2,2′-bipyridine ligands and two O atoms from a 3,5-dinitro-2-oxidobenzoate ligand, displaying a distorted octahedral coordination geometry. The crystal structure involves C—H⋯O h...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967915/ https://www.ncbi.nlm.nih.gov/pubmed/21581544 http://dx.doi.org/10.1107/S1600536808041974 |
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author | Zhong, Chun-Long Jiang, Xiu-Rong Wen, De-Cai |
author_facet | Zhong, Chun-Long Jiang, Xiu-Rong Wen, De-Cai |
author_sort | Zhong, Chun-Long |
collection | PubMed |
description | In the title compound, [Co(C(7)H(2)N(2)O(7))(C(10)H(8)N(2))(2)], the Co(II) atom is coordinated by four N atoms from two 2,2′-bipyridine ligands and two O atoms from a 3,5-dinitro-2-oxidobenzoate ligand, displaying a distorted octahedral coordination geometry. The crystal structure involves C—H⋯O hydrogen bonds between the 2,2′-bipyridine ligands and the carboxylate and NO(2) groups of the 3,5-dinitro-2-oxidobenzoate ligand. |
format | Text |
id | pubmed-2967915 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29679152010-12-30 Bis(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitro-2-oxidobenzoato-κ(2) O (1),O (2))cobalt(II) Zhong, Chun-Long Jiang, Xiu-Rong Wen, De-Cai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(7)H(2)N(2)O(7))(C(10)H(8)N(2))(2)], the Co(II) atom is coordinated by four N atoms from two 2,2′-bipyridine ligands and two O atoms from a 3,5-dinitro-2-oxidobenzoate ligand, displaying a distorted octahedral coordination geometry. The crystal structure involves C—H⋯O hydrogen bonds between the 2,2′-bipyridine ligands and the carboxylate and NO(2) groups of the 3,5-dinitro-2-oxidobenzoate ligand. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967915/ /pubmed/21581544 http://dx.doi.org/10.1107/S1600536808041974 Text en © Zhong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhong, Chun-Long Jiang, Xiu-Rong Wen, De-Cai Bis(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitro-2-oxidobenzoato-κ(2) O (1),O (2))cobalt(II) |
title | Bis(2,2′-bipyridine-κ(2)
N,N′)(3,5-dinitro-2-oxidobenzoato-κ(2)
O
(1),O
(2))cobalt(II) |
title_full | Bis(2,2′-bipyridine-κ(2)
N,N′)(3,5-dinitro-2-oxidobenzoato-κ(2)
O
(1),O
(2))cobalt(II) |
title_fullStr | Bis(2,2′-bipyridine-κ(2)
N,N′)(3,5-dinitro-2-oxidobenzoato-κ(2)
O
(1),O
(2))cobalt(II) |
title_full_unstemmed | Bis(2,2′-bipyridine-κ(2)
N,N′)(3,5-dinitro-2-oxidobenzoato-κ(2)
O
(1),O
(2))cobalt(II) |
title_short | Bis(2,2′-bipyridine-κ(2)
N,N′)(3,5-dinitro-2-oxidobenzoato-κ(2)
O
(1),O
(2))cobalt(II) |
title_sort | bis(2,2′-bipyridine-κ(2)
n,n′)(3,5-dinitro-2-oxidobenzoato-κ(2)
o
(1),o
(2))cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967915/ https://www.ncbi.nlm.nih.gov/pubmed/21581544 http://dx.doi.org/10.1107/S1600536808041974 |
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