Cargando…
catena-Poly[[bis(nitrato-κ(2) O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ(2) N (4):N (4′)]
In the title compound, [Cu(NO(3))(2)(C(6)H(6)N(4)S(4))](n), the Cu(II) atom, occupying a crystallographic inversion centre, is six-coordinated by two N atoms of two 2,2′-[1,2-ethanediylbis(thio)]bis[1,3,4-thiadiazole] ligands in trans positions, and four O atoms from two symmetry-related opposi...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967916/ https://www.ncbi.nlm.nih.gov/pubmed/21581546 http://dx.doi.org/10.1107/S1600536808041202 |
_version_ | 1782189725538320384 |
---|---|
author | Huang, Hua-Ming Ju, Feng-Yang Wang, Jian-Ge Qin, Jian-Hua |
author_facet | Huang, Hua-Ming Ju, Feng-Yang Wang, Jian-Ge Qin, Jian-Hua |
author_sort | Huang, Hua-Ming |
collection | PubMed |
description | In the title compound, [Cu(NO(3))(2)(C(6)H(6)N(4)S(4))](n), the Cu(II) atom, occupying a crystallographic inversion centre, is six-coordinated by two N atoms of two 2,2′-[1,2-ethanediylbis(thio)]bis[1,3,4-thiadiazole] ligands in trans positions, and four O atoms from two symmetry-related opposite nitrate anions, which are asymmetrically bonded, resulting in a strong distorted octahedral geometry of the central atom. The ethane group is equally disordered over two sites via another inversion centre. The bridging bidentate 2,2′-[1,2-ethanediylbis(thio)]bis[1,3,4-thiadiazole] ligands link the Cu(II) centres into a one-dimensional chain. The chains are interconnected via intermolecular S⋯O interactions [3.044 (4) and 3.084 (5) Å] and weak C—H⋯O hydrogen bonds, generating a three-dimensional supramolecular structure. |
format | Text |
id | pubmed-2967916 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29679162010-12-30 catena-Poly[[bis(nitrato-κ(2) O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ(2) N (4):N (4′)] Huang, Hua-Ming Ju, Feng-Yang Wang, Jian-Ge Qin, Jian-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(NO(3))(2)(C(6)H(6)N(4)S(4))](n), the Cu(II) atom, occupying a crystallographic inversion centre, is six-coordinated by two N atoms of two 2,2′-[1,2-ethanediylbis(thio)]bis[1,3,4-thiadiazole] ligands in trans positions, and four O atoms from two symmetry-related opposite nitrate anions, which are asymmetrically bonded, resulting in a strong distorted octahedral geometry of the central atom. The ethane group is equally disordered over two sites via another inversion centre. The bridging bidentate 2,2′-[1,2-ethanediylbis(thio)]bis[1,3,4-thiadiazole] ligands link the Cu(II) centres into a one-dimensional chain. The chains are interconnected via intermolecular S⋯O interactions [3.044 (4) and 3.084 (5) Å] and weak C—H⋯O hydrogen bonds, generating a three-dimensional supramolecular structure. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967916/ /pubmed/21581546 http://dx.doi.org/10.1107/S1600536808041202 Text en © Huang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Huang, Hua-Ming Ju, Feng-Yang Wang, Jian-Ge Qin, Jian-Hua catena-Poly[[bis(nitrato-κ(2) O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ(2) N (4):N (4′)] |
title |
catena-Poly[[bis(nitrato-κ(2)
O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ(2)
N
(4):N
(4′)] |
title_full |
catena-Poly[[bis(nitrato-κ(2)
O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ(2)
N
(4):N
(4′)] |
title_fullStr |
catena-Poly[[bis(nitrato-κ(2)
O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ(2)
N
(4):N
(4′)] |
title_full_unstemmed |
catena-Poly[[bis(nitrato-κ(2)
O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ(2)
N
(4):N
(4′)] |
title_short |
catena-Poly[[bis(nitrato-κ(2)
O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ(2)
N
(4):N
(4′)] |
title_sort | catena-poly[[bis(nitrato-κ(2)
o,o′)copper(ii)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thiadiazole-κ(2)
n
(4):n
(4′)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967916/ https://www.ncbi.nlm.nih.gov/pubmed/21581546 http://dx.doi.org/10.1107/S1600536808041202 |
work_keys_str_mv | AT huanghuaming catenapolybisnitratok2oocopperiim22ethane12diyldithiodi134thiadiazolek2n4n4 AT jufengyang catenapolybisnitratok2oocopperiim22ethane12diyldithiodi134thiadiazolek2n4n4 AT wangjiange catenapolybisnitratok2oocopperiim22ethane12diyldithiodi134thiadiazolek2n4n4 AT qinjianhua catenapolybisnitratok2oocopperiim22ethane12diyldithiodi134thiadiazolek2n4n4 |