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catena-Poly[[bis­(nitrato-κ(2) O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thia­diazole-κ(2) N (4):N (4′)]

In the title compound, [Cu(NO(3))(2)(C(6)H(6)N(4)S(4))](n), the Cu(II) atom, occupying a crystallographic inversion centre, is six-coordinated by two N atoms of two 2,2′-[1,2-ethane­diyl­bis­(thio)]bis­[1,3,4-thia­diazole] ligands in trans positions, and four O atoms from two symmetry-related opposi...

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Detalles Bibliográficos
Autores principales: Huang, Hua-Ming, Ju, Feng-Yang, Wang, Jian-Ge, Qin, Jian-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967916/
https://www.ncbi.nlm.nih.gov/pubmed/21581546
http://dx.doi.org/10.1107/S1600536808041202
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author Huang, Hua-Ming
Ju, Feng-Yang
Wang, Jian-Ge
Qin, Jian-Hua
author_facet Huang, Hua-Ming
Ju, Feng-Yang
Wang, Jian-Ge
Qin, Jian-Hua
author_sort Huang, Hua-Ming
collection PubMed
description In the title compound, [Cu(NO(3))(2)(C(6)H(6)N(4)S(4))](n), the Cu(II) atom, occupying a crystallographic inversion centre, is six-coordinated by two N atoms of two 2,2′-[1,2-ethane­diyl­bis­(thio)]bis­[1,3,4-thia­diazole] ligands in trans positions, and four O atoms from two symmetry-related opposite nitrate anions, which are asymmetrically bonded, resulting in a strong distorted octa­hedral geometry of the central atom. The ethane group is equally disordered over two sites via another inversion centre. The bridging bidentate 2,2′-[1,2-ethanediylbis(thio)]bis­[1,3,4-thia­diazole] ligands link the Cu(II) centres into a one-dimensional chain. The chains are inter­connected via inter­molecular S⋯O inter­actions [3.044 (4) and 3.084 (5) Å] and weak C—H⋯O hydrogen bonds, generating a three-dimensional supra­molecular structure.
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spelling pubmed-29679162010-12-30 catena-Poly[[bis­(nitrato-κ(2) O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thia­diazole-κ(2) N (4):N (4′)] Huang, Hua-Ming Ju, Feng-Yang Wang, Jian-Ge Qin, Jian-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(NO(3))(2)(C(6)H(6)N(4)S(4))](n), the Cu(II) atom, occupying a crystallographic inversion centre, is six-coordinated by two N atoms of two 2,2′-[1,2-ethane­diyl­bis­(thio)]bis­[1,3,4-thia­diazole] ligands in trans positions, and four O atoms from two symmetry-related opposite nitrate anions, which are asymmetrically bonded, resulting in a strong distorted octa­hedral geometry of the central atom. The ethane group is equally disordered over two sites via another inversion centre. The bridging bidentate 2,2′-[1,2-ethanediylbis(thio)]bis­[1,3,4-thia­diazole] ligands link the Cu(II) centres into a one-dimensional chain. The chains are inter­connected via inter­molecular S⋯O inter­actions [3.044 (4) and 3.084 (5) Å] and weak C—H⋯O hydrogen bonds, generating a three-dimensional supra­molecular structure. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967916/ /pubmed/21581546 http://dx.doi.org/10.1107/S1600536808041202 Text en © Huang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Hua-Ming
Ju, Feng-Yang
Wang, Jian-Ge
Qin, Jian-Hua
catena-Poly[[bis­(nitrato-κ(2) O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thia­diazole-κ(2) N (4):N (4′)]
title catena-Poly[[bis­(nitrato-κ(2) O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thia­diazole-κ(2) N (4):N (4′)]
title_full catena-Poly[[bis­(nitrato-κ(2) O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thia­diazole-κ(2) N (4):N (4′)]
title_fullStr catena-Poly[[bis­(nitrato-κ(2) O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thia­diazole-κ(2) N (4):N (4′)]
title_full_unstemmed catena-Poly[[bis­(nitrato-κ(2) O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thia­diazole-κ(2) N (4):N (4′)]
title_short catena-Poly[[bis­(nitrato-κ(2) O,O′)copper(II)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thia­diazole-κ(2) N (4):N (4′)]
title_sort catena-poly[[bis­(nitrato-κ(2) o,o′)copper(ii)]-μ-2,2′-(ethane-1,2-diyldithio)di-1,3,4-thia­diazole-κ(2) n (4):n (4′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967916/
https://www.ncbi.nlm.nih.gov/pubmed/21581546
http://dx.doi.org/10.1107/S1600536808041202
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