Tetra­kis(μ-2-chloro-4-nitro­benzoato-κ(2) O:O′)bis­[aqua­copper(II)]

In the title binuclear copper(II) complex, [Cu(2)(C(7)H(3)ClNO(4))(4)(H(2)O)(2)], each of the two independent Cu(II) center is five-coordinated by four O atoms of the carboxyl­ate groups in the basal plane and one O atom of a water mol­ecule in the apical position, in a distorted square-pyramidal ge...

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Detalles Bibliográficos
Autores principales: Lim, Eng Khoon, Teoh, Siang Guan, Razak, Ibrahim Abdul, Jebas, Samuel Robinson, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967917/
https://www.ncbi.nlm.nih.gov/pubmed/21581547
http://dx.doi.org/10.1107/S1600536808041986
Descripción
Sumario:In the title binuclear copper(II) complex, [Cu(2)(C(7)H(3)ClNO(4))(4)(H(2)O)(2)], each of the two independent Cu(II) center is five-coordinated by four O atoms of the carboxyl­ate groups in the basal plane and one O atom of a water mol­ecule in the apical position, in a distorted square-pyramidal geometry. The Cu—Cu distance is 2.6458 (4) Å. In the crystal structure, the dinuclear units are linked into a three-dimensional network by O—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds. One of the Cl atoms is disordered over two positions with occupancies of 0.650 (2) and 0.350 (2).

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