Cargando…
Tetrakis(μ-2-chloro-4-nitrobenzoato-κ(2) O:O′)bis[aquacopper(II)]
In the title binuclear copper(II) complex, [Cu(2)(C(7)H(3)ClNO(4))(4)(H(2)O)(2)], each of the two independent Cu(II) center is five-coordinated by four O atoms of the carboxylate groups in the basal plane and one O atom of a water molecule in the apical position, in a distorted square-pyramidal ge...
| Autores principales: | , , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967917/ https://www.ncbi.nlm.nih.gov/pubmed/21581547 http://dx.doi.org/10.1107/S1600536808041986 |
| _version_ | 1782189725777395712 |
|---|---|
| author | Lim, Eng Khoon Teoh, Siang Guan Razak, Ibrahim Abdul Jebas, Samuel Robinson Fun, Hoong-Kun |
| author_facet | Lim, Eng Khoon Teoh, Siang Guan Razak, Ibrahim Abdul Jebas, Samuel Robinson Fun, Hoong-Kun |
| author_sort | Lim, Eng Khoon |
| collection | PubMed |
| description | In the title binuclear copper(II) complex, [Cu(2)(C(7)H(3)ClNO(4))(4)(H(2)O)(2)], each of the two independent Cu(II) center is five-coordinated by four O atoms of the carboxylate groups in the basal plane and one O atom of a water molecule in the apical position, in a distorted square-pyramidal geometry. The Cu—Cu distance is 2.6458 (4) Å. In the crystal structure, the dinuclear units are linked into a three-dimensional network by O—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds. One of the Cl atoms is disordered over two positions with occupancies of 0.650 (2) and 0.350 (2). |
| format | Text |
| id | pubmed-2967917 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29679172010-12-30 Tetrakis(μ-2-chloro-4-nitrobenzoato-κ(2) O:O′)bis[aquacopper(II)] Lim, Eng Khoon Teoh, Siang Guan Razak, Ibrahim Abdul Jebas, Samuel Robinson Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title binuclear copper(II) complex, [Cu(2)(C(7)H(3)ClNO(4))(4)(H(2)O)(2)], each of the two independent Cu(II) center is five-coordinated by four O atoms of the carboxylate groups in the basal plane and one O atom of a water molecule in the apical position, in a distorted square-pyramidal geometry. The Cu—Cu distance is 2.6458 (4) Å. In the crystal structure, the dinuclear units are linked into a three-dimensional network by O—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds. One of the Cl atoms is disordered over two positions with occupancies of 0.650 (2) and 0.350 (2). International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967917/ /pubmed/21581547 http://dx.doi.org/10.1107/S1600536808041986 Text en © Lim et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lim, Eng Khoon Teoh, Siang Guan Razak, Ibrahim Abdul Jebas, Samuel Robinson Fun, Hoong-Kun Tetrakis(μ-2-chloro-4-nitrobenzoato-κ(2) O:O′)bis[aquacopper(II)] |
| title | Tetrakis(μ-2-chloro-4-nitrobenzoato-κ(2)
O:O′)bis[aquacopper(II)] |
| title_full | Tetrakis(μ-2-chloro-4-nitrobenzoato-κ(2)
O:O′)bis[aquacopper(II)] |
| title_fullStr | Tetrakis(μ-2-chloro-4-nitrobenzoato-κ(2)
O:O′)bis[aquacopper(II)] |
| title_full_unstemmed | Tetrakis(μ-2-chloro-4-nitrobenzoato-κ(2)
O:O′)bis[aquacopper(II)] |
| title_short | Tetrakis(μ-2-chloro-4-nitrobenzoato-κ(2)
O:O′)bis[aquacopper(II)] |
| title_sort | tetrakis(μ-2-chloro-4-nitrobenzoato-κ(2)
o:o′)bis[aquacopper(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967917/ https://www.ncbi.nlm.nih.gov/pubmed/21581547 http://dx.doi.org/10.1107/S1600536808041986 |
| work_keys_str_mv | AT limengkhoon tetrakism2chloro4nitrobenzoatok2oobisaquacopperii AT teohsiangguan tetrakism2chloro4nitrobenzoatok2oobisaquacopperii AT razakibrahimabdul tetrakism2chloro4nitrobenzoatok2oobisaquacopperii AT jebassamuelrobinson tetrakism2chloro4nitrobenzoatok2oobisaquacopperii AT funhoongkun tetrakism2chloro4nitrobenzoatok2oobisaquacopperii |