Cargando…

Diammonium aqua­(ethyl­ene­diamine­tetra­acetato)iron(II) trihydrate

In the title compound, (NH(4))(2)[Fe(C(10)H(12)N(2)O(8))(H(2)O)]·3H(2)O, the Fe(II) center is in a distorted penta­gonal-bipyramidal geometry. Two carboxyl­ate O and two N atoms from the ethyl­enediaminetetra­acetate (EDTA) ion and one O atom from coordinated water comprise the equatorial plane. Two...

Descripción completa

Detalles Bibliográficos
Autores principales: Huang, Hua-Ming, Yang, Hong-Bing, Li, Xiang-Yu, Ren, Fang-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967920/
https://www.ncbi.nlm.nih.gov/pubmed/21581550
http://dx.doi.org/10.1107/S1600536808042190
_version_ 1782189726473650176
author Huang, Hua-Ming
Yang, Hong-Bing
Li, Xiang-Yu
Ren, Fang-Fang
author_facet Huang, Hua-Ming
Yang, Hong-Bing
Li, Xiang-Yu
Ren, Fang-Fang
author_sort Huang, Hua-Ming
collection PubMed
description In the title compound, (NH(4))(2)[Fe(C(10)H(12)N(2)O(8))(H(2)O)]·3H(2)O, the Fe(II) center is in a distorted penta­gonal-bipyramidal geometry. Two carboxyl­ate O and two N atoms from the ethyl­enediaminetetra­acetate (EDTA) ion and one O atom from coordinated water comprise the equatorial plane. Two other carboxyl­ate O atoms from the EDTA ion occupy the apical sites. Both ammonium cations and all water mol­ecules function as hydrogen-bond donors, and ten N—H⋯O and nine O—H⋯O hydrogen bonds form a three-dimensional network between the complex anions, cations and the water mol­ecules.
format Text
id pubmed-2967920
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29679202010-12-30 Diammonium aqua­(ethyl­ene­diamine­tetra­acetato)iron(II) trihydrate Huang, Hua-Ming Yang, Hong-Bing Li, Xiang-Yu Ren, Fang-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (NH(4))(2)[Fe(C(10)H(12)N(2)O(8))(H(2)O)]·3H(2)O, the Fe(II) center is in a distorted penta­gonal-bipyramidal geometry. Two carboxyl­ate O and two N atoms from the ethyl­enediaminetetra­acetate (EDTA) ion and one O atom from coordinated water comprise the equatorial plane. Two other carboxyl­ate O atoms from the EDTA ion occupy the apical sites. Both ammonium cations and all water mol­ecules function as hydrogen-bond donors, and ten N—H⋯O and nine O—H⋯O hydrogen bonds form a three-dimensional network between the complex anions, cations and the water mol­ecules. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967920/ /pubmed/21581550 http://dx.doi.org/10.1107/S1600536808042190 Text en © Huang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Hua-Ming
Yang, Hong-Bing
Li, Xiang-Yu
Ren, Fang-Fang
Diammonium aqua­(ethyl­ene­diamine­tetra­acetato)iron(II) trihydrate
title Diammonium aqua­(ethyl­ene­diamine­tetra­acetato)iron(II) trihydrate
title_full Diammonium aqua­(ethyl­ene­diamine­tetra­acetato)iron(II) trihydrate
title_fullStr Diammonium aqua­(ethyl­ene­diamine­tetra­acetato)iron(II) trihydrate
title_full_unstemmed Diammonium aqua­(ethyl­ene­diamine­tetra­acetato)iron(II) trihydrate
title_short Diammonium aqua­(ethyl­ene­diamine­tetra­acetato)iron(II) trihydrate
title_sort diammonium aqua­(ethyl­ene­diamine­tetra­acetato)iron(ii) trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967920/
https://www.ncbi.nlm.nih.gov/pubmed/21581550
http://dx.doi.org/10.1107/S1600536808042190
work_keys_str_mv AT huanghuaming diammoniumaquaethylenediaminetetraacetatoironiitrihydrate
AT yanghongbing diammoniumaquaethylenediaminetetraacetatoironiitrihydrate
AT lixiangyu diammoniumaquaethylenediaminetetraacetatoironiitrihydrate
AT renfangfang diammoniumaquaethylenediaminetetraacetatoironiitrihydrate