Aqua­(imino­diacetato-κ(3) O,N,O′)(1,10-phenanthroline-κ(2) N,N′)zinc(II) sesquihydrate

The imino­diacetate dianion in the title compound, [Zn(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·1.5H(2)O, chelates to the Zn(II) center with its N and two O atoms. The metal atom is also chelated by the N-heterocycle and coordinated by one water molecule, leading to a distorted octahedral environment....

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Detalles Bibliográficos
Autores principales: Ng, Hwa Loong, Ng, Chew Hee, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967921/
https://www.ncbi.nlm.nih.gov/pubmed/21581551
http://dx.doi.org/10.1107/S1600536808042141
Descripción
Sumario:The imino­diacetate dianion in the title compound, [Zn(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·1.5H(2)O, chelates to the Zn(II) center with its N and two O atoms. The metal atom is also chelated by the N-heterocycle and coordinated by one water molecule, leading to a distorted octahedral environment. The dianion, and coordinated and uncoordinated water mol­ecules inter­act through O—H⋯O hydrogen bonds, generating a three-dimensional network. One of the two uncoordinated water mol­ecules has half-site occupancy. The crystal studied was a non-merohedral twin with a 15% twin component.

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