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Aqua(iminodiacetato-κ(3) O,N,O′)(1,10-phenanthroline-κ(2) N,N′)zinc(II) sesquihydrate
The iminodiacetate dianion in the title compound, [Zn(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·1.5H(2)O, chelates to the Zn(II) center with its N and two O atoms. The metal atom is also chelated by the N-heterocycle and coordinated by one water molecule, leading to a distorted octahedral environment....
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967921/ https://www.ncbi.nlm.nih.gov/pubmed/21581551 http://dx.doi.org/10.1107/S1600536808042141 |
| _version_ | 1782189726708531200 |
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| author | Ng, Hwa Loong Ng, Chew Hee Ng, Seik Weng |
| author_facet | Ng, Hwa Loong Ng, Chew Hee Ng, Seik Weng |
| author_sort | Ng, Hwa Loong |
| collection | PubMed |
| description | The iminodiacetate dianion in the title compound, [Zn(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·1.5H(2)O, chelates to the Zn(II) center with its N and two O atoms. The metal atom is also chelated by the N-heterocycle and coordinated by one water molecule, leading to a distorted octahedral environment. The dianion, and coordinated and uncoordinated water molecules interact through O—H⋯O hydrogen bonds, generating a three-dimensional network. One of the two uncoordinated water molecules has half-site occupancy. The crystal studied was a non-merohedral twin with a 15% twin component. |
| format | Text |
| id | pubmed-2967921 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29679212010-12-30 Aqua(iminodiacetato-κ(3) O,N,O′)(1,10-phenanthroline-κ(2) N,N′)zinc(II) sesquihydrate Ng, Hwa Loong Ng, Chew Hee Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The iminodiacetate dianion in the title compound, [Zn(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·1.5H(2)O, chelates to the Zn(II) center with its N and two O atoms. The metal atom is also chelated by the N-heterocycle and coordinated by one water molecule, leading to a distorted octahedral environment. The dianion, and coordinated and uncoordinated water molecules interact through O—H⋯O hydrogen bonds, generating a three-dimensional network. One of the two uncoordinated water molecules has half-site occupancy. The crystal studied was a non-merohedral twin with a 15% twin component. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967921/ /pubmed/21581551 http://dx.doi.org/10.1107/S1600536808042141 Text en © Ng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ng, Hwa Loong Ng, Chew Hee Ng, Seik Weng Aqua(iminodiacetato-κ(3) O,N,O′)(1,10-phenanthroline-κ(2) N,N′)zinc(II) sesquihydrate |
| title | Aqua(iminodiacetato-κ(3)
O,N,O′)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) sesquihydrate |
| title_full | Aqua(iminodiacetato-κ(3)
O,N,O′)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) sesquihydrate |
| title_fullStr | Aqua(iminodiacetato-κ(3)
O,N,O′)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) sesquihydrate |
| title_full_unstemmed | Aqua(iminodiacetato-κ(3)
O,N,O′)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) sesquihydrate |
| title_short | Aqua(iminodiacetato-κ(3)
O,N,O′)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) sesquihydrate |
| title_sort | aqua(iminodiacetato-κ(3)
o,n,o′)(1,10-phenanthroline-κ(2)
n,n′)zinc(ii) sesquihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967921/ https://www.ncbi.nlm.nih.gov/pubmed/21581551 http://dx.doi.org/10.1107/S1600536808042141 |
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