(η(5)-Cyclo­penta­dien­yl)bis­(triphenyl­phosphane)cobalt(I)–toluene–n-hexane (1/0.20/0.25)

The title compound, [Co(C(5)H(5))(C(18)H(15)P)(2)]·0.2C(7)H(8)·0.25C(6)H(14), was synthesized by the reaction of cobaltocene, Cp(2)Co, with elemental lithium in tetra­hydro­furan in the presence of two equivalents of PPh(3). The mol­ecular structure displays a cobalt(I) center in a distorted trigona...

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Detalles Bibliográficos
Autores principales: Hapke, Marko, Spannenberg, Anke
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967925/
https://www.ncbi.nlm.nih.gov/pubmed/21581556
http://dx.doi.org/10.1107/S1600536808042268
Descripción
Sumario:The title compound, [Co(C(5)H(5))(C(18)H(15)P)(2)]·0.2C(7)H(8)·0.25C(6)H(14), was synthesized by the reaction of cobaltocene, Cp(2)Co, with elemental lithium in tetra­hydro­furan in the presence of two equivalents of PPh(3). The mol­ecular structure displays a cobalt(I) center in a distorted trigonal-planar coordination environment, with one Cp and two phosphane ligands. There are two crystallographically independent mol­ecules in the asymmetric unit besides the disordered solvent molecules.

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