(η(5)-Cyclo­penta­dien­yl)bis­(triphenyl­phosphane)cobalt(I)–toluene–n-hexane (1/0.20/0.25)

The title compound, [Co(C(5)H(5))(C(18)H(15)P)(2)]·0.2C(7)H(8)·0.25C(6)H(14), was synthesized by the reaction of cobaltocene, Cp(2)Co, with elemental lithium in tetra­hydro­furan in the presence of two equivalents of PPh(3). The mol­ecular structure displays a cobalt(I) center in a distorted trigona...

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Detalles Bibliográficos
Autores principales: Hapke, Marko, Spannenberg, Anke
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967925/
https://www.ncbi.nlm.nih.gov/pubmed/21581556
http://dx.doi.org/10.1107/S1600536808042268
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author Hapke, Marko
Spannenberg, Anke
author_facet Hapke, Marko
Spannenberg, Anke
author_sort Hapke, Marko
collection PubMed
description The title compound, [Co(C(5)H(5))(C(18)H(15)P)(2)]·0.2C(7)H(8)·0.25C(6)H(14), was synthesized by the reaction of cobaltocene, Cp(2)Co, with elemental lithium in tetra­hydro­furan in the presence of two equivalents of PPh(3). The mol­ecular structure displays a cobalt(I) center in a distorted trigonal-planar coordination environment, with one Cp and two phosphane ligands. There are two crystallographically independent mol­ecules in the asymmetric unit besides the disordered solvent molecules.
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spelling pubmed-29679252010-12-30 (η(5)-Cyclo­penta­dien­yl)bis­(triphenyl­phosphane)cobalt(I)–toluene–n-hexane (1/0.20/0.25) Hapke, Marko Spannenberg, Anke Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(5)H(5))(C(18)H(15)P)(2)]·0.2C(7)H(8)·0.25C(6)H(14), was synthesized by the reaction of cobaltocene, Cp(2)Co, with elemental lithium in tetra­hydro­furan in the presence of two equivalents of PPh(3). The mol­ecular structure displays a cobalt(I) center in a distorted trigonal-planar coordination environment, with one Cp and two phosphane ligands. There are two crystallographically independent mol­ecules in the asymmetric unit besides the disordered solvent molecules. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967925/ /pubmed/21581556 http://dx.doi.org/10.1107/S1600536808042268 Text en © Hapke and Spannenberg 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hapke, Marko
Spannenberg, Anke
(η(5)-Cyclo­penta­dien­yl)bis­(triphenyl­phosphane)cobalt(I)–toluene–n-hexane (1/0.20/0.25)
title (η(5)-Cyclo­penta­dien­yl)bis­(triphenyl­phosphane)cobalt(I)–toluene–n-hexane (1/0.20/0.25)
title_full (η(5)-Cyclo­penta­dien­yl)bis­(triphenyl­phosphane)cobalt(I)–toluene–n-hexane (1/0.20/0.25)
title_fullStr (η(5)-Cyclo­penta­dien­yl)bis­(triphenyl­phosphane)cobalt(I)–toluene–n-hexane (1/0.20/0.25)
title_full_unstemmed (η(5)-Cyclo­penta­dien­yl)bis­(triphenyl­phosphane)cobalt(I)–toluene–n-hexane (1/0.20/0.25)
title_short (η(5)-Cyclo­penta­dien­yl)bis­(triphenyl­phosphane)cobalt(I)–toluene–n-hexane (1/0.20/0.25)
title_sort (η(5)-cyclo­penta­dien­yl)bis­(triphenyl­phosphane)cobalt(i)–toluene–n-hexane (1/0.20/0.25)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967925/
https://www.ncbi.nlm.nih.gov/pubmed/21581556
http://dx.doi.org/10.1107/S1600536808042268
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AT spannenberganke ē5cyclopentadienylbistriphenylphosphanecobaltitoluenenhexane1020025

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