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Bis(μ-pyridazine-3-carboxylato-κ(2) O:O′)bis[aquadioxido(pyridazine-3-carboxylato-κ(2) N (2),O)uranium(VI)] dihydrate
The structure of the binuclear title complex, [U(2)(C(5)H(3)N(2)O(2))(4)O(4)(H(2)O)(2)]·2H(2)O, is composed of centrosymmetric dimers in which each UO(2) (2+) ion is coordinated by two ligand molecules. One donates its N,O-bonding group and the other donates both carboxylate O atoms. Each of the l...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967926/ https://www.ncbi.nlm.nih.gov/pubmed/21581557 http://dx.doi.org/10.1107/S1600536808042219 |
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author | Leciejewicz, Janusz Starosta, Wojciech |
author_facet | Leciejewicz, Janusz Starosta, Wojciech |
author_sort | Leciejewicz, Janusz |
collection | PubMed |
description | The structure of the binuclear title complex, [U(2)(C(5)H(3)N(2)O(2))(4)O(4)(H(2)O)(2)]·2H(2)O, is composed of centrosymmetric dimers in which each UO(2) (2+) ion is coordinated by two ligand molecules. One donates its N,O-bonding group and the other donates both carboxylate O atoms. Each of the latter bridges adjacent uranyl ions. The coordination environment of the metal center is a distorted pentagonal bipyramid. The dimers are interconnected by O—H⋯O hydrogen bonds between coordinated and uncoordinated water molecules and carboxylate O atoms. An intramolecular O—H⋯N interaction is also present. |
format | Text |
id | pubmed-2967926 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29679262010-12-30 Bis(μ-pyridazine-3-carboxylato-κ(2) O:O′)bis[aquadioxido(pyridazine-3-carboxylato-κ(2) N (2),O)uranium(VI)] dihydrate Leciejewicz, Janusz Starosta, Wojciech Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the binuclear title complex, [U(2)(C(5)H(3)N(2)O(2))(4)O(4)(H(2)O)(2)]·2H(2)O, is composed of centrosymmetric dimers in which each UO(2) (2+) ion is coordinated by two ligand molecules. One donates its N,O-bonding group and the other donates both carboxylate O atoms. Each of the latter bridges adjacent uranyl ions. The coordination environment of the metal center is a distorted pentagonal bipyramid. The dimers are interconnected by O—H⋯O hydrogen bonds between coordinated and uncoordinated water molecules and carboxylate O atoms. An intramolecular O—H⋯N interaction is also present. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967926/ /pubmed/21581557 http://dx.doi.org/10.1107/S1600536808042219 Text en © Leciejewicz and Starosta 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Leciejewicz, Janusz Starosta, Wojciech Bis(μ-pyridazine-3-carboxylato-κ(2) O:O′)bis[aquadioxido(pyridazine-3-carboxylato-κ(2) N (2),O)uranium(VI)] dihydrate |
title | Bis(μ-pyridazine-3-carboxylato-κ(2)
O:O′)bis[aquadioxido(pyridazine-3-carboxylato-κ(2)
N
(2),O)uranium(VI)] dihydrate |
title_full | Bis(μ-pyridazine-3-carboxylato-κ(2)
O:O′)bis[aquadioxido(pyridazine-3-carboxylato-κ(2)
N
(2),O)uranium(VI)] dihydrate |
title_fullStr | Bis(μ-pyridazine-3-carboxylato-κ(2)
O:O′)bis[aquadioxido(pyridazine-3-carboxylato-κ(2)
N
(2),O)uranium(VI)] dihydrate |
title_full_unstemmed | Bis(μ-pyridazine-3-carboxylato-κ(2)
O:O′)bis[aquadioxido(pyridazine-3-carboxylato-κ(2)
N
(2),O)uranium(VI)] dihydrate |
title_short | Bis(μ-pyridazine-3-carboxylato-κ(2)
O:O′)bis[aquadioxido(pyridazine-3-carboxylato-κ(2)
N
(2),O)uranium(VI)] dihydrate |
title_sort | bis(μ-pyridazine-3-carboxylato-κ(2)
o:o′)bis[aquadioxido(pyridazine-3-carboxylato-κ(2)
n
(2),o)uranium(vi)] dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967926/ https://www.ncbi.nlm.nih.gov/pubmed/21581557 http://dx.doi.org/10.1107/S1600536808042219 |
work_keys_str_mv | AT leciejewiczjanusz bismpyridazine3carboxylatok2oobisaquadioxidopyridazine3carboxylatok2n2ouraniumvidihydrate AT starostawojciech bismpyridazine3carboxylatok2oobisaquadioxidopyridazine3carboxylatok2n2ouraniumvidihydrate |