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Bis(μ-pyridazine-3-carboxyl­ato-κ(2) O:O′)bis­[aqua­dioxido(pyridazine-3-carboxyl­ato-κ(2) N (2),O)uranium(VI)] dihydrate

The structure of the binuclear title complex, [U(2)(C(5)H(3)N(2)O(2))(4)O(4)(H(2)O)(2)]·2H(2)O, is composed of centrosymmetric dimers in which each UO(2) (2+) ion is coordinated by two ligand mol­ecules. One donates its N,O-bonding group and the other donates both carboxyl­ate O atoms. Each of the l...

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Detalles Bibliográficos
Autores principales: Leciejewicz, Janusz, Starosta, Wojciech
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967926/
https://www.ncbi.nlm.nih.gov/pubmed/21581557
http://dx.doi.org/10.1107/S1600536808042219
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author Leciejewicz, Janusz
Starosta, Wojciech
author_facet Leciejewicz, Janusz
Starosta, Wojciech
author_sort Leciejewicz, Janusz
collection PubMed
description The structure of the binuclear title complex, [U(2)(C(5)H(3)N(2)O(2))(4)O(4)(H(2)O)(2)]·2H(2)O, is composed of centrosymmetric dimers in which each UO(2) (2+) ion is coordinated by two ligand mol­ecules. One donates its N,O-bonding group and the other donates both carboxyl­ate O atoms. Each of the latter bridges adjacent uranyl ions. The coordination environment of the metal center is a distorted penta­gonal bipyramid. The dimers are inter­connected by O—H⋯O hydrogen bonds between coordinated and uncoordinated water mol­ecules and carboxyl­ate O atoms. An intra­molecular O—H⋯N inter­action is also present.
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spelling pubmed-29679262010-12-30 Bis(μ-pyridazine-3-carboxyl­ato-κ(2) O:O′)bis­[aqua­dioxido(pyridazine-3-carboxyl­ato-κ(2) N (2),O)uranium(VI)] dihydrate Leciejewicz, Janusz Starosta, Wojciech Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the binuclear title complex, [U(2)(C(5)H(3)N(2)O(2))(4)O(4)(H(2)O)(2)]·2H(2)O, is composed of centrosymmetric dimers in which each UO(2) (2+) ion is coordinated by two ligand mol­ecules. One donates its N,O-bonding group and the other donates both carboxyl­ate O atoms. Each of the latter bridges adjacent uranyl ions. The coordination environment of the metal center is a distorted penta­gonal bipyramid. The dimers are inter­connected by O—H⋯O hydrogen bonds between coordinated and uncoordinated water mol­ecules and carboxyl­ate O atoms. An intra­molecular O—H⋯N inter­action is also present. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967926/ /pubmed/21581557 http://dx.doi.org/10.1107/S1600536808042219 Text en © Leciejewicz and Starosta 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Leciejewicz, Janusz
Starosta, Wojciech
Bis(μ-pyridazine-3-carboxyl­ato-κ(2) O:O′)bis­[aqua­dioxido(pyridazine-3-carboxyl­ato-κ(2) N (2),O)uranium(VI)] dihydrate
title Bis(μ-pyridazine-3-carboxyl­ato-κ(2) O:O′)bis­[aqua­dioxido(pyridazine-3-carboxyl­ato-κ(2) N (2),O)uranium(VI)] dihydrate
title_full Bis(μ-pyridazine-3-carboxyl­ato-κ(2) O:O′)bis­[aqua­dioxido(pyridazine-3-carboxyl­ato-κ(2) N (2),O)uranium(VI)] dihydrate
title_fullStr Bis(μ-pyridazine-3-carboxyl­ato-κ(2) O:O′)bis­[aqua­dioxido(pyridazine-3-carboxyl­ato-κ(2) N (2),O)uranium(VI)] dihydrate
title_full_unstemmed Bis(μ-pyridazine-3-carboxyl­ato-κ(2) O:O′)bis­[aqua­dioxido(pyridazine-3-carboxyl­ato-κ(2) N (2),O)uranium(VI)] dihydrate
title_short Bis(μ-pyridazine-3-carboxyl­ato-κ(2) O:O′)bis­[aqua­dioxido(pyridazine-3-carboxyl­ato-κ(2) N (2),O)uranium(VI)] dihydrate
title_sort bis(μ-pyridazine-3-carboxyl­ato-κ(2) o:o′)bis­[aqua­dioxido(pyridazine-3-carboxyl­ato-κ(2) n (2),o)uranium(vi)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967926/
https://www.ncbi.nlm.nih.gov/pubmed/21581557
http://dx.doi.org/10.1107/S1600536808042219
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