(2,4-Di-tert-butyl-6-{(E)-[(E)-2-(2-methoxy­benzyl­ideneamino)cyclo­hexyl]imino­meth­yl}phenolato)dimethyl­aluminum(III)

The title compound, [Al(CH(3))(2)(C(29)H(39)N(2)O(2))], exhibits disorder of one of the tert-butyl groups on the Schiff base ligand, where each methyl group is located over two sites, with occupancy factors of 0.57 (1) and 0.43 (1). The geometry around the Al(III) atom is distorted tetra­hedral, def...

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Detalles Bibliográficos
Autor principal: Wu, Jin-Cai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967927/
https://www.ncbi.nlm.nih.gov/pubmed/21581558
http://dx.doi.org/10.1107/S1600536808041858
Descripción
Sumario:The title compound, [Al(CH(3))(2)(C(29)H(39)N(2)O(2))], exhibits disorder of one of the tert-butyl groups on the Schiff base ligand, where each methyl group is located over two sites, with occupancy factors of 0.57 (1) and 0.43 (1). The geometry around the Al(III) atom is distorted tetra­hedral, defined by two methyl groups, one N and one O atom from the Schiff base ligand.

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