Bis(η(7)-cyclo­hepta­trien­yl)tri-μ-hydrido-dimolybdenum(0,I)

In the title compound, [Mo(2)(η(7)-C(7)H(7))(2)(μ-H)(3)], which displays crystallographic mirror symmetry, two (η(7)-C(7)H(7))Mo units are linked along the Mo—Mo axis by three bridging hydride ligands. The Mo—Mo distance is 2.5732 (4) Å. The perpendicular distances of the Mo atoms from the C(7) plan...

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Detalles Bibliográficos
Autores principales: Jones, Peter G., Hrib, Cristian G., Randoll, Sören, Wu, Xian, Tamm, Matthias
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967928/
https://www.ncbi.nlm.nih.gov/pubmed/21581559
http://dx.doi.org/10.1107/S1600536808042244
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author Jones, Peter G.
Hrib, Cristian G.
Randoll, Sören
Wu, Xian
Tamm, Matthias
author_facet Jones, Peter G.
Hrib, Cristian G.
Randoll, Sören
Wu, Xian
Tamm, Matthias
author_sort Jones, Peter G.
collection PubMed
description In the title compound, [Mo(2)(η(7)-C(7)H(7))(2)(μ-H)(3)], which displays crystallographic mirror symmetry, two (η(7)-C(7)H(7))Mo units are linked along the Mo—Mo axis by three bridging hydride ligands. The Mo—Mo distance is 2.5732 (4) Å. The perpendicular distances of the Mo atoms from the C(7) planes are 1.5827 (8) and 1.5814 (8) Å, with individual Mo—C bond lengths in the range 2.261 (2)–2.2789 (14) Å. Mo—H distances range from 1.77 (3) to 1.85 (4) Å, with Mo—H—Mo angles of 89 (2) and 92 (1)°.
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spelling pubmed-29679282010-12-30 Bis(η(7)-cyclo­hepta­trien­yl)tri-μ-hydrido-dimolybdenum(0,I) Jones, Peter G. Hrib, Cristian G. Randoll, Sören Wu, Xian Tamm, Matthias Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mo(2)(η(7)-C(7)H(7))(2)(μ-H)(3)], which displays crystallographic mirror symmetry, two (η(7)-C(7)H(7))Mo units are linked along the Mo—Mo axis by three bridging hydride ligands. The Mo—Mo distance is 2.5732 (4) Å. The perpendicular distances of the Mo atoms from the C(7) planes are 1.5827 (8) and 1.5814 (8) Å, with individual Mo—C bond lengths in the range 2.261 (2)–2.2789 (14) Å. Mo—H distances range from 1.77 (3) to 1.85 (4) Å, with Mo—H—Mo angles of 89 (2) and 92 (1)°. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967928/ /pubmed/21581559 http://dx.doi.org/10.1107/S1600536808042244 Text en © Jones et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jones, Peter G.
Hrib, Cristian G.
Randoll, Sören
Wu, Xian
Tamm, Matthias
Bis(η(7)-cyclo­hepta­trien­yl)tri-μ-hydrido-dimolybdenum(0,I)
title Bis(η(7)-cyclo­hepta­trien­yl)tri-μ-hydrido-dimolybdenum(0,I)
title_full Bis(η(7)-cyclo­hepta­trien­yl)tri-μ-hydrido-dimolybdenum(0,I)
title_fullStr Bis(η(7)-cyclo­hepta­trien­yl)tri-μ-hydrido-dimolybdenum(0,I)
title_full_unstemmed Bis(η(7)-cyclo­hepta­trien­yl)tri-μ-hydrido-dimolybdenum(0,I)
title_short Bis(η(7)-cyclo­hepta­trien­yl)tri-μ-hydrido-dimolybdenum(0,I)
title_sort bis(η(7)-cyclo­hepta­trien­yl)tri-μ-hydrido-dimolybdenum(0,i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967928/
https://www.ncbi.nlm.nih.gov/pubmed/21581559
http://dx.doi.org/10.1107/S1600536808042244
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AT wuxian bisē7cycloheptatrienyltrimhydridodimolybdenum0i
AT tammmatthias bisē7cycloheptatrienyltrimhydridodimolybdenum0i

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