μ-Oxido-bis­[(2-chloro­nicotinato-κO)triphenyl­anti­mony(V)]

A new dinuclear triphenyl­anti­mony(V) derivative with an oxide bridge, [Sb(2)(C(6)H(5))(6)(C(6)H(3)ClNO(2))(2)O], has been synthesized. Each Sb atom is five-coordianted by three C atoms and two O atoms in a distorted trigonal-bipyramidal geometry. Metal centers are bridged by a μ(2)-oxide functiona...

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Detalles Bibliográficos
Autores principales: Quan, Li, Yin, Handong, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967930/
https://www.ncbi.nlm.nih.gov/pubmed/21581561
http://dx.doi.org/10.1107/S1600536808042335
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author Quan, Li
Yin, Handong
Wang, Daqi
author_facet Quan, Li
Yin, Handong
Wang, Daqi
author_sort Quan, Li
collection PubMed
description A new dinuclear triphenyl­anti­mony(V) derivative with an oxide bridge, [Sb(2)(C(6)H(5))(6)(C(6)H(3)ClNO(2))(2)O], has been synthesized. Each Sb atom is five-coordianted by three C atoms and two O atoms in a distorted trigonal-bipyramidal geometry. Metal centers are bridged by a μ(2)-oxide functionality, and phenyl substituents on Sb atoms are in an staggered arrangement. The Sb—O—Sb bridge displays a bent geometry with an angle of 165.1 (4)°. Mol­ecules inter­act in the crystal through weak C—H⋯O and C—H⋯N inter­molecular hydrogen bonds.
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spelling pubmed-29679302010-12-30 μ-Oxido-bis­[(2-chloro­nicotinato-κO)triphenyl­anti­mony(V)] Quan, Li Yin, Handong Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers A new dinuclear triphenyl­anti­mony(V) derivative with an oxide bridge, [Sb(2)(C(6)H(5))(6)(C(6)H(3)ClNO(2))(2)O], has been synthesized. Each Sb atom is five-coordianted by three C atoms and two O atoms in a distorted trigonal-bipyramidal geometry. Metal centers are bridged by a μ(2)-oxide functionality, and phenyl substituents on Sb atoms are in an staggered arrangement. The Sb—O—Sb bridge displays a bent geometry with an angle of 165.1 (4)°. Mol­ecules inter­act in the crystal through weak C—H⋯O and C—H⋯N inter­molecular hydrogen bonds. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2967930/ /pubmed/21581561 http://dx.doi.org/10.1107/S1600536808042335 Text en © Quan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Quan, Li
Yin, Handong
Wang, Daqi
μ-Oxido-bis­[(2-chloro­nicotinato-κO)triphenyl­anti­mony(V)]
title μ-Oxido-bis­[(2-chloro­nicotinato-κO)triphenyl­anti­mony(V)]
title_full μ-Oxido-bis­[(2-chloro­nicotinato-κO)triphenyl­anti­mony(V)]
title_fullStr μ-Oxido-bis­[(2-chloro­nicotinato-κO)triphenyl­anti­mony(V)]
title_full_unstemmed μ-Oxido-bis­[(2-chloro­nicotinato-κO)triphenyl­anti­mony(V)]
title_short μ-Oxido-bis­[(2-chloro­nicotinato-κO)triphenyl­anti­mony(V)]
title_sort μ-oxido-bis­[(2-chloro­nicotinato-κo)triphenyl­anti­mony(v)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967930/
https://www.ncbi.nlm.nih.gov/pubmed/21581561
http://dx.doi.org/10.1107/S1600536808042335
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AT yinhandong moxidobis2chloronicotinatokotriphenylantimonyv
AT wangdaqi moxidobis2chloronicotinatokotriphenylantimonyv

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