1-Dichloro­acetyl-3,3-dimethyl-2,6-diphenyl­piperidin-4-one

In the title compound, C(21)H(21)Cl(2)NO(2), the piperidine ring adopts a distorted boat conformation. The two phenyl rings are approximately perpendicular to each other, with a dihedral angle of 86.12 (7)°. Mol­ecules are linked into centrosymmetric dimers by pairs of bifurcated C—H⋯O hydrogen bond...

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Detalles Bibliográficos
Autores principales: Kavitha, T., Ponnuswamy, S., Jamesh, M., Umamaheshwari, J., Ponnuswamy, M. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967931/
https://www.ncbi.nlm.nih.gov/pubmed/21581563
http://dx.doi.org/10.1107/S1600536808040051
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author Kavitha, T.
Ponnuswamy, S.
Jamesh, M.
Umamaheshwari, J.
Ponnuswamy, M. N.
author_facet Kavitha, T.
Ponnuswamy, S.
Jamesh, M.
Umamaheshwari, J.
Ponnuswamy, M. N.
author_sort Kavitha, T.
collection PubMed
description In the title compound, C(21)H(21)Cl(2)NO(2), the piperidine ring adopts a distorted boat conformation. The two phenyl rings are approximately perpendicular to each other, with a dihedral angle of 86.12 (7)°. Mol­ecules are linked into centrosymmetric dimers by pairs of bifurcated C—H⋯O hydrogen bonds, forming R (2) (2)(10) and R (2) (2)(14) ring motifs, and an intramolecular C—H⋯O link also occurs.
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spelling pubmed-29679312010-12-30 1-Dichloro­acetyl-3,3-dimethyl-2,6-diphenyl­piperidin-4-one Kavitha, T. Ponnuswamy, S. Jamesh, M. Umamaheshwari, J. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(21)Cl(2)NO(2), the piperidine ring adopts a distorted boat conformation. The two phenyl rings are approximately perpendicular to each other, with a dihedral angle of 86.12 (7)°. Mol­ecules are linked into centrosymmetric dimers by pairs of bifurcated C—H⋯O hydrogen bonds, forming R (2) (2)(10) and R (2) (2)(14) ring motifs, and an intramolecular C—H⋯O link also occurs. International Union of Crystallography 2008-12-03 /pmc/articles/PMC2967931/ /pubmed/21581563 http://dx.doi.org/10.1107/S1600536808040051 Text en © Kavitha et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kavitha, T.
Ponnuswamy, S.
Jamesh, M.
Umamaheshwari, J.
Ponnuswamy, M. N.
1-Dichloro­acetyl-3,3-dimethyl-2,6-diphenyl­piperidin-4-one
title 1-Dichloro­acetyl-3,3-dimethyl-2,6-diphenyl­piperidin-4-one
title_full 1-Dichloro­acetyl-3,3-dimethyl-2,6-diphenyl­piperidin-4-one
title_fullStr 1-Dichloro­acetyl-3,3-dimethyl-2,6-diphenyl­piperidin-4-one
title_full_unstemmed 1-Dichloro­acetyl-3,3-dimethyl-2,6-diphenyl­piperidin-4-one
title_short 1-Dichloro­acetyl-3,3-dimethyl-2,6-diphenyl­piperidin-4-one
title_sort 1-dichloro­acetyl-3,3-dimethyl-2,6-diphenyl­piperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967931/
https://www.ncbi.nlm.nih.gov/pubmed/21581563
http://dx.doi.org/10.1107/S1600536808040051
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AT jameshm 1dichloroacetyl33dimethyl26diphenylpiperidin4one
AT umamaheshwarij 1dichloroacetyl33dimethyl26diphenylpiperidin4one
AT ponnuswamymn 1dichloroacetyl33dimethyl26diphenylpiperidin4one

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