Diethyl 2-[(2-benzyl-1-phenyl­sulfonyl-1H-indol-3-yl)methyl­ene]malonate

In the title compound, C(29)H(27)NO(6)S, the sulfonyl-bound phenyl ring is almost perpendicular to the indole ring system [dihedral angle = 87.96 (6)°], while the benzyl­phenyl ring is oriented at an angle of 76.8 (7)°. An intra­molecular C—H⋯O hydrogen bond is observed. In the crystal structure, mo...

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Detalles Bibliográficos
Autores principales: Kavitha, T., Thenmozhi, M., Dhayalan, V., Mohanakrishnan, A. K., Ponnuswamy, M. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967933/
https://www.ncbi.nlm.nih.gov/pubmed/21581581
http://dx.doi.org/10.1107/S160053680804004X
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author Kavitha, T.
Thenmozhi, M.
Dhayalan, V.
Mohanakrishnan, A. K.
Ponnuswamy, M. N.
author_facet Kavitha, T.
Thenmozhi, M.
Dhayalan, V.
Mohanakrishnan, A. K.
Ponnuswamy, M. N.
author_sort Kavitha, T.
collection PubMed
description In the title compound, C(29)H(27)NO(6)S, the sulfonyl-bound phenyl ring is almost perpendicular to the indole ring system [dihedral angle = 87.96 (6)°], while the benzyl­phenyl ring is oriented at an angle of 76.8 (7)°. An intra­molecular C—H⋯O hydrogen bond is observed. In the crystal structure, mol­ecules are linked into a zigzag C(10) chain along the b axis by inter­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-29679332010-12-30 Diethyl 2-[(2-benzyl-1-phenyl­sulfonyl-1H-indol-3-yl)methyl­ene]malonate Kavitha, T. Thenmozhi, M. Dhayalan, V. Mohanakrishnan, A. K. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(29)H(27)NO(6)S, the sulfonyl-bound phenyl ring is almost perpendicular to the indole ring system [dihedral angle = 87.96 (6)°], while the benzyl­phenyl ring is oriented at an angle of 76.8 (7)°. An intra­molecular C—H⋯O hydrogen bond is observed. In the crystal structure, mol­ecules are linked into a zigzag C(10) chain along the b axis by inter­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2008-12-03 /pmc/articles/PMC2967933/ /pubmed/21581581 http://dx.doi.org/10.1107/S160053680804004X Text en © Kavitha et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kavitha, T.
Thenmozhi, M.
Dhayalan, V.
Mohanakrishnan, A. K.
Ponnuswamy, M. N.
Diethyl 2-[(2-benzyl-1-phenyl­sulfonyl-1H-indol-3-yl)methyl­ene]malonate
title Diethyl 2-[(2-benzyl-1-phenyl­sulfonyl-1H-indol-3-yl)methyl­ene]malonate
title_full Diethyl 2-[(2-benzyl-1-phenyl­sulfonyl-1H-indol-3-yl)methyl­ene]malonate
title_fullStr Diethyl 2-[(2-benzyl-1-phenyl­sulfonyl-1H-indol-3-yl)methyl­ene]malonate
title_full_unstemmed Diethyl 2-[(2-benzyl-1-phenyl­sulfonyl-1H-indol-3-yl)methyl­ene]malonate
title_short Diethyl 2-[(2-benzyl-1-phenyl­sulfonyl-1H-indol-3-yl)methyl­ene]malonate
title_sort diethyl 2-[(2-benzyl-1-phenyl­sulfonyl-1h-indol-3-yl)methyl­ene]malonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967933/
https://www.ncbi.nlm.nih.gov/pubmed/21581581
http://dx.doi.org/10.1107/S160053680804004X
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AT mohanakrishnanak diethyl22benzyl1phenylsulfonyl1hindol3ylmethylenemalonate
AT ponnuswamymn diethyl22benzyl1phenylsulfonyl1hindol3ylmethylenemalonate

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