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4-Carb­oxy-2-methyl-1H-imidazol-3-ium-5-carboxyl­ate monohydrate

In the title compound, C(6)H(6)N(2)O(4)·H(2)O, one carboxyl group is deprotonated and one imidazole N atom is protonated. The organic mol­ecule, excluding methyl H atoms, is essentially planar, with an r.m.s. deviation of 0.0156 (1) Å. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds l...

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Detalles Bibliográficos
Autor principal: Guo, Yu-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967941/
https://www.ncbi.nlm.nih.gov/pubmed/21581665
http://dx.doi.org/10.1107/S1600536808040221
Descripción
Sumario:In the title compound, C(6)H(6)N(2)O(4)·H(2)O, one carboxyl group is deprotonated and one imidazole N atom is protonated. The organic mol­ecule, excluding methyl H atoms, is essentially planar, with an r.m.s. deviation of 0.0156 (1) Å. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link mol­ecules into chains along the b axis; these chains are further linked via O—H⋯O hydrogen bonds involving the water O atoms and carboxyl O atoms, generating a two-dimensional supra­molecular framework.