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N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-2-chloro-N-(2-chloro­benzoyl)benzamide

The title compound, C(24)H(12)BrCl(2)NO(4), was synthesized from 2-amino-3-bromo-1,4-naphthoquinone and 2-chloro­benzoyl chloride. The crystal structure shows that each of the chloro­phenyl rings is inclined at about 60° to the naphthoquinone ring system. The two chloro­phenyl rings adopt a conforma...

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Detalles Bibliográficos
Autores principales: Akinboye, Emmanuel S., Butcher, Ray J., Brandy, Yakini, Adesiyun, Tolulope A., Bakare, Oladapo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967943/
https://www.ncbi.nlm.nih.gov/pubmed/21581667
http://dx.doi.org/10.1107/S1600536808039214
Descripción
Sumario:The title compound, C(24)H(12)BrCl(2)NO(4), was synthesized from 2-amino-3-bromo-1,4-naphthoquinone and 2-chloro­benzoyl chloride. The crystal structure shows that each of the chloro­phenyl rings is inclined at about 60° to the naphthoquinone ring system. The two chloro­phenyl rings adopt a conformation that ensures that chlorine substituents are anti so as to reduce electronic repulsion. An examination of the packing shows close O⋯Br and Cl⋯Cl contacts of 2.947 (2) and 3.346 (1) Å, respectively. In addition, the molecules are linked by weak intermolecular C—H⋯O and C—H⋯Cl interactions.