N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-2-chloro-N-(2-chloro­benzoyl)benzamide

The title compound, C(24)H(12)BrCl(2)NO(4), was synthesized from 2-amino-3-bromo-1,4-naphthoquinone and 2-chloro­benzoyl chloride. The crystal structure shows that each of the chloro­phenyl rings is inclined at about 60° to the naphthoquinone ring system. The two chloro­phenyl rings adopt a conforma...

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Autores principales: Akinboye, Emmanuel S., Butcher, Ray J., Brandy, Yakini, Adesiyun, Tolulope A., Bakare, Oladapo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967943/
https://www.ncbi.nlm.nih.gov/pubmed/21581667
http://dx.doi.org/10.1107/S1600536808039214
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author Akinboye, Emmanuel S.
Butcher, Ray J.
Brandy, Yakini
Adesiyun, Tolulope A.
Bakare, Oladapo
author_facet Akinboye, Emmanuel S.
Butcher, Ray J.
Brandy, Yakini
Adesiyun, Tolulope A.
Bakare, Oladapo
author_sort Akinboye, Emmanuel S.
collection PubMed
description The title compound, C(24)H(12)BrCl(2)NO(4), was synthesized from 2-amino-3-bromo-1,4-naphthoquinone and 2-chloro­benzoyl chloride. The crystal structure shows that each of the chloro­phenyl rings is inclined at about 60° to the naphthoquinone ring system. The two chloro­phenyl rings adopt a conformation that ensures that chlorine substituents are anti so as to reduce electronic repulsion. An examination of the packing shows close O⋯Br and Cl⋯Cl contacts of 2.947 (2) and 3.346 (1) Å, respectively. In addition, the molecules are linked by weak intermolecular C—H⋯O and C—H⋯Cl interactions.
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spelling pubmed-29679432010-12-30 N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-2-chloro-N-(2-chloro­benzoyl)benzamide Akinboye, Emmanuel S. Butcher, Ray J. Brandy, Yakini Adesiyun, Tolulope A. Bakare, Oladapo Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(12)BrCl(2)NO(4), was synthesized from 2-amino-3-bromo-1,4-naphthoquinone and 2-chloro­benzoyl chloride. The crystal structure shows that each of the chloro­phenyl rings is inclined at about 60° to the naphthoquinone ring system. The two chloro­phenyl rings adopt a conformation that ensures that chlorine substituents are anti so as to reduce electronic repulsion. An examination of the packing shows close O⋯Br and Cl⋯Cl contacts of 2.947 (2) and 3.346 (1) Å, respectively. In addition, the molecules are linked by weak intermolecular C—H⋯O and C—H⋯Cl interactions. International Union of Crystallography 2008-12-06 /pmc/articles/PMC2967943/ /pubmed/21581667 http://dx.doi.org/10.1107/S1600536808039214 Text en © Akinboye et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akinboye, Emmanuel S.
Butcher, Ray J.
Brandy, Yakini
Adesiyun, Tolulope A.
Bakare, Oladapo
N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-2-chloro-N-(2-chloro­benzoyl)benzamide
title N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-2-chloro-N-(2-chloro­benzoyl)benzamide
title_full N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-2-chloro-N-(2-chloro­benzoyl)benzamide
title_fullStr N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-2-chloro-N-(2-chloro­benzoyl)benzamide
title_full_unstemmed N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-2-chloro-N-(2-chloro­benzoyl)benzamide
title_short N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-2-chloro-N-(2-chloro­benzoyl)benzamide
title_sort n-(3-bromo-1,4-dioxo-1,4-dihydro-2-naphth­yl)-2-chloro-n-(2-chloro­benzoyl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967943/
https://www.ncbi.nlm.nih.gov/pubmed/21581667
http://dx.doi.org/10.1107/S1600536808039214
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AT bakareoladapo n3bromo14dioxo14dihydro2naphthyl2chloron2chlorobenzoylbenzamide

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