N′-(2-Hydr­oxy-3-methoxy­benzyl­idene)-1,3-benzodioxole-5-carbohydrazide monohydrate

Single crystals of the title compound, C(16)H(14)N(2)O(5)·H(2)O, were obtained from a condensation reaction of 1,3-benzodioxole-5-carbohydrazide and 3-methoxy­salicylaldehyde in a 95% ethanol solution. The asymmetric unit consists of a Schiff base mol­ecule, which assumes an E configuration with res...

Descripción completa

Detalles Bibliográficos
Autor principal: Du, Chun-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967948/
https://www.ncbi.nlm.nih.gov/pubmed/21581672
http://dx.doi.org/10.1107/S1600536808040117
_version_ 1782189733169856512
author Du, Chun-Lin
author_facet Du, Chun-Lin
author_sort Du, Chun-Lin
collection PubMed
description Single crystals of the title compound, C(16)H(14)N(2)O(5)·H(2)O, were obtained from a condensation reaction of 1,3-benzodioxole-5-carbohydrazide and 3-methoxy­salicylaldehyde in a 95% ethanol solution. The asymmetric unit consists of a Schiff base mol­ecule, which assumes an E configuration with respect to the C=N bond, and a water mol­ecule of crystallization. The dihedral angle between the two substituted benzene rings is 12.7 (2)°. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, forming layers parallel to the bc plane.
format Text
id pubmed-2967948
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29679482010-12-30 N′-(2-Hydr­oxy-3-methoxy­benzyl­idene)-1,3-benzodioxole-5-carbohydrazide monohydrate Du, Chun-Lin Acta Crystallogr Sect E Struct Rep Online Organic Papers Single crystals of the title compound, C(16)H(14)N(2)O(5)·H(2)O, were obtained from a condensation reaction of 1,3-benzodioxole-5-carbohydrazide and 3-methoxy­salicylaldehyde in a 95% ethanol solution. The asymmetric unit consists of a Schiff base mol­ecule, which assumes an E configuration with respect to the C=N bond, and a water mol­ecule of crystallization. The dihedral angle between the two substituted benzene rings is 12.7 (2)°. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, forming layers parallel to the bc plane. International Union of Crystallography 2008-12-06 /pmc/articles/PMC2967948/ /pubmed/21581672 http://dx.doi.org/10.1107/S1600536808040117 Text en © Chun-Lin Du 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Du, Chun-Lin
N′-(2-Hydr­oxy-3-methoxy­benzyl­idene)-1,3-benzodioxole-5-carbohydrazide monohydrate
title N′-(2-Hydr­oxy-3-methoxy­benzyl­idene)-1,3-benzodioxole-5-carbohydrazide monohydrate
title_full N′-(2-Hydr­oxy-3-methoxy­benzyl­idene)-1,3-benzodioxole-5-carbohydrazide monohydrate
title_fullStr N′-(2-Hydr­oxy-3-methoxy­benzyl­idene)-1,3-benzodioxole-5-carbohydrazide monohydrate
title_full_unstemmed N′-(2-Hydr­oxy-3-methoxy­benzyl­idene)-1,3-benzodioxole-5-carbohydrazide monohydrate
title_short N′-(2-Hydr­oxy-3-methoxy­benzyl­idene)-1,3-benzodioxole-5-carbohydrazide monohydrate
title_sort n′-(2-hydr­oxy-3-methoxy­benzyl­idene)-1,3-benzodioxole-5-carbohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967948/
https://www.ncbi.nlm.nih.gov/pubmed/21581672
http://dx.doi.org/10.1107/S1600536808040117
work_keys_str_mv AT duchunlin n2hydroxy3methoxybenzylidene13benzodioxole5carbohydrazidemonohydrate

Ejemplares similares