9-Ethyl-10-methyl­acridinium trifluoro­methane­sulfonate

In the mol­ecule of the title compound, C(16)H(16)N(+)·CF(3)SO(3) (−), the central ring adopts a flattened-boat conformation, and the two aromatic rings are oriented at a dihedral angle of 3.94 (2)°. In the crystal structure, weak inter­molecular hydrogen bonds link the mol­ecules. There are π–π con...

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Autores principales: Zadykowicz, Beata, Wera, Michał, Sikorski, Artur, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967949/
https://www.ncbi.nlm.nih.gov/pubmed/21581674
http://dx.doi.org/10.1107/S1600536808039676
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author Zadykowicz, Beata
Wera, Michał
Sikorski, Artur
Błażejowski, Jerzy
author_facet Zadykowicz, Beata
Wera, Michał
Sikorski, Artur
Błażejowski, Jerzy
author_sort Zadykowicz, Beata
collection PubMed
description In the mol­ecule of the title compound, C(16)H(16)N(+)·CF(3)SO(3) (−), the central ring adopts a flattened-boat conformation, and the two aromatic rings are oriented at a dihedral angle of 3.94 (2)°. In the crystal structure, weak inter­molecular hydrogen bonds link the mol­ecules. There are π–π contacts between the aromatic rings and the central ring and one of the aromatic rings [centroid–centroid distances = 3.874 (2), 3.945 (2) and 3.814 (2) Å]. There is also an S—O⋯π contact between the central ring and one of the O atoms of the anion.
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spelling pubmed-29679492010-12-30 9-Ethyl-10-methyl­acridinium trifluoro­methane­sulfonate Zadykowicz, Beata Wera, Michał Sikorski, Artur Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(16)H(16)N(+)·CF(3)SO(3) (−), the central ring adopts a flattened-boat conformation, and the two aromatic rings are oriented at a dihedral angle of 3.94 (2)°. In the crystal structure, weak inter­molecular hydrogen bonds link the mol­ecules. There are π–π contacts between the aromatic rings and the central ring and one of the aromatic rings [centroid–centroid distances = 3.874 (2), 3.945 (2) and 3.814 (2) Å]. There is also an S—O⋯π contact between the central ring and one of the O atoms of the anion. International Union of Crystallography 2008-12-06 /pmc/articles/PMC2967949/ /pubmed/21581674 http://dx.doi.org/10.1107/S1600536808039676 Text en © Zadykowicz et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zadykowicz, Beata
Wera, Michał
Sikorski, Artur
Błażejowski, Jerzy
9-Ethyl-10-methyl­acridinium trifluoro­methane­sulfonate
title 9-Ethyl-10-methyl­acridinium trifluoro­methane­sulfonate
title_full 9-Ethyl-10-methyl­acridinium trifluoro­methane­sulfonate
title_fullStr 9-Ethyl-10-methyl­acridinium trifluoro­methane­sulfonate
title_full_unstemmed 9-Ethyl-10-methyl­acridinium trifluoro­methane­sulfonate
title_short 9-Ethyl-10-methyl­acridinium trifluoro­methane­sulfonate
title_sort 9-ethyl-10-methyl­acridinium trifluoro­methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967949/
https://www.ncbi.nlm.nih.gov/pubmed/21581674
http://dx.doi.org/10.1107/S1600536808039676
work_keys_str_mv AT zadykowiczbeata 9ethyl10methylacridiniumtrifluoromethanesulfonate
AT weramichał 9ethyl10methylacridiniumtrifluoromethanesulfonate
AT sikorskiartur 9ethyl10methylacridiniumtrifluoromethanesulfonate
AT błazejowskijerzy 9ethyl10methylacridiniumtrifluoromethanesulfonate

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