Cargando…
1,3-Dimethoxy-2,3-dihydro-1H-isoindole-2-carbothioamide
In the molecule of the title compound, C(11)H(14)N(2)O(2)S, the five-membered ring adopts an envelope conformation and an intramolecular N—H⋯O hydrogen bond occurs. Intramolecular N—H⋯O, C—H⋯S and C—H⋯N hydrogen bonds result in the formation of two five- and one six-membered rings, having twisted...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967958/ https://www.ncbi.nlm.nih.gov/pubmed/21581684 http://dx.doi.org/10.1107/S1600536808040075 |
_version_ | 1782189735508180992 |
---|---|
author | Maliha, Bushra Tariq, Muhammad Ilyas Tahir, M. Nawaz Hussain, Ishtiaq Ali, Muhammad |
author_facet | Maliha, Bushra Tariq, Muhammad Ilyas Tahir, M. Nawaz Hussain, Ishtiaq Ali, Muhammad |
author_sort | Maliha, Bushra |
collection | PubMed |
description | In the molecule of the title compound, C(11)H(14)N(2)O(2)S, the five-membered ring adopts an envelope conformation and an intramolecular N—H⋯O hydrogen bond occurs. Intramolecular N—H⋯O, C—H⋯S and C—H⋯N hydrogen bonds result in the formation of two five- and one six-membered rings, having twisted conformations. In the crystal structure, intermolecular N—H⋯O, N—H⋯S and C—H⋯S hydrogen bonds link the molecules, forming polymeric sheets. The π–π contacts between the isoindole ring systems, [centroid–centroid distances = 3.5883 (8) and 4.0619 (8) Å] may further stabilize the structure. A C—H⋯π interactions also occur. |
format | Text |
id | pubmed-2967958 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29679582010-12-30 1,3-Dimethoxy-2,3-dihydro-1H-isoindole-2-carbothioamide Maliha, Bushra Tariq, Muhammad Ilyas Tahir, M. Nawaz Hussain, Ishtiaq Ali, Muhammad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(11)H(14)N(2)O(2)S, the five-membered ring adopts an envelope conformation and an intramolecular N—H⋯O hydrogen bond occurs. Intramolecular N—H⋯O, C—H⋯S and C—H⋯N hydrogen bonds result in the formation of two five- and one six-membered rings, having twisted conformations. In the crystal structure, intermolecular N—H⋯O, N—H⋯S and C—H⋯S hydrogen bonds link the molecules, forming polymeric sheets. The π–π contacts between the isoindole ring systems, [centroid–centroid distances = 3.5883 (8) and 4.0619 (8) Å] may further stabilize the structure. A C—H⋯π interactions also occur. International Union of Crystallography 2008-12-06 /pmc/articles/PMC2967958/ /pubmed/21581684 http://dx.doi.org/10.1107/S1600536808040075 Text en © Maliha et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Maliha, Bushra Tariq, Muhammad Ilyas Tahir, M. Nawaz Hussain, Ishtiaq Ali, Muhammad 1,3-Dimethoxy-2,3-dihydro-1H-isoindole-2-carbothioamide |
title | 1,3-Dimethoxy-2,3-dihydro-1H-isoindole-2-carbothioamide |
title_full | 1,3-Dimethoxy-2,3-dihydro-1H-isoindole-2-carbothioamide |
title_fullStr | 1,3-Dimethoxy-2,3-dihydro-1H-isoindole-2-carbothioamide |
title_full_unstemmed | 1,3-Dimethoxy-2,3-dihydro-1H-isoindole-2-carbothioamide |
title_short | 1,3-Dimethoxy-2,3-dihydro-1H-isoindole-2-carbothioamide |
title_sort | 1,3-dimethoxy-2,3-dihydro-1h-isoindole-2-carbothioamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967958/ https://www.ncbi.nlm.nih.gov/pubmed/21581684 http://dx.doi.org/10.1107/S1600536808040075 |
work_keys_str_mv | AT malihabushra 13dimethoxy23dihydro1hisoindole2carbothioamide AT tariqmuhammadilyas 13dimethoxy23dihydro1hisoindole2carbothioamide AT tahirmnawaz 13dimethoxy23dihydro1hisoindole2carbothioamide AT hussainishtiaq 13dimethoxy23dihydro1hisoindole2carbothioamide AT alimuhammad 13dimethoxy23dihydro1hisoindole2carbothioamide |