Cargando…
(1R,3S)-1,1′-(1,3-Dihydro-2-benzofuran-1,3-diyl)bis(1,3-dimethylurea)
In the molecule of the title compound, C(14)H(20)N(4)O(3), the five-membered ring adopts an envelope conformation with the O atom displaced by 0.207 (3) Å from the plane of the other ring atoms. Intramolecular C—H⋯O hydrogen bonds result in the formation of three five-membered rings having envelop...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967959/ https://www.ncbi.nlm.nih.gov/pubmed/21581685 http://dx.doi.org/10.1107/S1600536808040828 |
_version_ | 1782189735739916288 |
---|---|
author | Maliha, Bushra Tariq, Muhammad Ilyas Tahir, M. Nawaz Hussain, Ishtiaq Siddiqui, Hamid Latif |
author_facet | Maliha, Bushra Tariq, Muhammad Ilyas Tahir, M. Nawaz Hussain, Ishtiaq Siddiqui, Hamid Latif |
author_sort | Maliha, Bushra |
collection | PubMed |
description | In the molecule of the title compound, C(14)H(20)N(4)O(3), the five-membered ring adopts an envelope conformation with the O atom displaced by 0.207 (3) Å from the plane of the other ring atoms. Intramolecular C—H⋯O hydrogen bonds result in the formation of three five-membered rings having envelope conformations. In the crystal structure, intermolecular N—H⋯O hydrogen bonds link the molecules, forming R (2) (2)(20) ring motifs, which produce two-dimensional polymeric sheets extending along the b axis. There are also two C—H⋯π interactions. The H atoms of one of the methyl groups are disordered over two positions and were refined with occupancies of 0.50. |
format | Text |
id | pubmed-2967959 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29679592010-12-30 (1R,3S)-1,1′-(1,3-Dihydro-2-benzofuran-1,3-diyl)bis(1,3-dimethylurea) Maliha, Bushra Tariq, Muhammad Ilyas Tahir, M. Nawaz Hussain, Ishtiaq Siddiqui, Hamid Latif Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(14)H(20)N(4)O(3), the five-membered ring adopts an envelope conformation with the O atom displaced by 0.207 (3) Å from the plane of the other ring atoms. Intramolecular C—H⋯O hydrogen bonds result in the formation of three five-membered rings having envelope conformations. In the crystal structure, intermolecular N—H⋯O hydrogen bonds link the molecules, forming R (2) (2)(20) ring motifs, which produce two-dimensional polymeric sheets extending along the b axis. There are also two C—H⋯π interactions. The H atoms of one of the methyl groups are disordered over two positions and were refined with occupancies of 0.50. International Union of Crystallography 2008-12-06 /pmc/articles/PMC2967959/ /pubmed/21581685 http://dx.doi.org/10.1107/S1600536808040828 Text en © Maliha et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Maliha, Bushra Tariq, Muhammad Ilyas Tahir, M. Nawaz Hussain, Ishtiaq Siddiqui, Hamid Latif (1R,3S)-1,1′-(1,3-Dihydro-2-benzofuran-1,3-diyl)bis(1,3-dimethylurea) |
title | (1R,3S)-1,1′-(1,3-Dihydro-2-benzofuran-1,3-diyl)bis(1,3-dimethylurea) |
title_full | (1R,3S)-1,1′-(1,3-Dihydro-2-benzofuran-1,3-diyl)bis(1,3-dimethylurea) |
title_fullStr | (1R,3S)-1,1′-(1,3-Dihydro-2-benzofuran-1,3-diyl)bis(1,3-dimethylurea) |
title_full_unstemmed | (1R,3S)-1,1′-(1,3-Dihydro-2-benzofuran-1,3-diyl)bis(1,3-dimethylurea) |
title_short | (1R,3S)-1,1′-(1,3-Dihydro-2-benzofuran-1,3-diyl)bis(1,3-dimethylurea) |
title_sort | (1r,3s)-1,1′-(1,3-dihydro-2-benzofuran-1,3-diyl)bis(1,3-dimethylurea) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967959/ https://www.ncbi.nlm.nih.gov/pubmed/21581685 http://dx.doi.org/10.1107/S1600536808040828 |
work_keys_str_mv | AT malihabushra 1r3s1113dihydro2benzofuran13diylbis13dimethylurea AT tariqmuhammadilyas 1r3s1113dihydro2benzofuran13diylbis13dimethylurea AT tahirmnawaz 1r3s1113dihydro2benzofuran13diylbis13dimethylurea AT hussainishtiaq 1r3s1113dihydro2benzofuran13diylbis13dimethylurea AT siddiquihamidlatif 1r3s1113dihydro2benzofuran13diylbis13dimethylurea |