2,4-Difluoro­phenyl­boronic acid

The mol­ecular structure of the title compound, C(6)H(5)BF(2)O(2), is essentially planar (mean deviation = 0.019 Å), indicating electronic delocalization between the dihydroxy­boryl group and the aromatic ring. In the crystal structure, inversion dimers linked by two O—H⋯O hydrogen bonds arise. An i...

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Detalles Bibliográficos
Autores principales: Rodríguez-Cuamatzi, Patricia, Tlahuext, Hugo, Höpfl, Herbert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967960/
https://www.ncbi.nlm.nih.gov/pubmed/21581686
http://dx.doi.org/10.1107/S1600536808040646
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author Rodríguez-Cuamatzi, Patricia
Tlahuext, Hugo
Höpfl, Herbert
author_facet Rodríguez-Cuamatzi, Patricia
Tlahuext, Hugo
Höpfl, Herbert
author_sort Rodríguez-Cuamatzi, Patricia
collection PubMed
description The mol­ecular structure of the title compound, C(6)H(5)BF(2)O(2), is essentially planar (mean deviation = 0.019 Å), indicating electronic delocalization between the dihydroxy­boryl group and the aromatic ring. In the crystal structure, inversion dimers linked by two O—H⋯O hydrogen bonds arise. An intra­molecular O—H⋯F hydrogen bond reinforces the conformation and the same H atom is also involved in an inter­molecular O—H⋯F link, leading to mol­ecular sheets in the crystal.
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spelling pubmed-29679602010-12-30 2,4-Difluoro­phenyl­boronic acid Rodríguez-Cuamatzi, Patricia Tlahuext, Hugo Höpfl, Herbert Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular structure of the title compound, C(6)H(5)BF(2)O(2), is essentially planar (mean deviation = 0.019 Å), indicating electronic delocalization between the dihydroxy­boryl group and the aromatic ring. In the crystal structure, inversion dimers linked by two O—H⋯O hydrogen bonds arise. An intra­molecular O—H⋯F hydrogen bond reinforces the conformation and the same H atom is also involved in an inter­molecular O—H⋯F link, leading to mol­ecular sheets in the crystal. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967960/ /pubmed/21581686 http://dx.doi.org/10.1107/S1600536808040646 Text en © Rodríguez-Cuamatzi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rodríguez-Cuamatzi, Patricia
Tlahuext, Hugo
Höpfl, Herbert
2,4-Difluoro­phenyl­boronic acid
title 2,4-Difluoro­phenyl­boronic acid
title_full 2,4-Difluoro­phenyl­boronic acid
title_fullStr 2,4-Difluoro­phenyl­boronic acid
title_full_unstemmed 2,4-Difluoro­phenyl­boronic acid
title_short 2,4-Difluoro­phenyl­boronic acid
title_sort 2,4-difluoro­phenyl­boronic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967960/
https://www.ncbi.nlm.nih.gov/pubmed/21581686
http://dx.doi.org/10.1107/S1600536808040646
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