Cargando…
3,3′-Bis(4-chlorophenyl)-2,2′-(m-phenylenedioxy)diquinazolin-4(3H)-one
In the title compound, C(34)H(20)Cl(2)N(4)O(4), the two quinazoline heterocyclic systems and the adjacent chlorobenzene rings are not coplanar, but oriented at dihedral angles of 66.66 (13) and 52.48 (12)°, respectively. The quinazoline ring systems are nearly planar, with dihedral angles between t...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967973/ https://www.ncbi.nlm.nih.gov/pubmed/21581700 http://dx.doi.org/10.1107/S1600536808040567 |
Sumario: | In the title compound, C(34)H(20)Cl(2)N(4)O(4), the two quinazoline heterocyclic systems and the adjacent chlorobenzene rings are not coplanar, but oriented at dihedral angles of 66.66 (13) and 52.48 (12)°, respectively. The quinazoline ring systems are nearly planar, with dihedral angles between the planes of the two rings of 5.43 (16) and 3.40 (14)°, and are oriented at dihedral angles of 79.73 (13) and 83.52 (13)° with respect to the adjacent benzene ring between them. Intermolecular C—H⋯O hydrogen bonds contribute to the stability of the structure. In addition, weak π–π stacking interactions [centroid-to-centroid distances = 3.872 (1) and 3.876 (1) Å] are observed in the crystal structure. |
---|