3,3′-Bis(4-chloro­phen­yl)-2,2′-(m-phenyl­enedi­oxy)diquinazolin-4(3H)-one

In the title compound, C(34)H(20)Cl(2)N(4)O(4), the two quinazoline heterocyclic systems and the adjacent chloro­benzene rings are not coplanar, but oriented at dihedral angles of 66.66 (13) and 52.48 (12)°, respectively. The quinazoline ring systems are nearly planar, with dihedral angles between t...

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Detalles Bibliográficos
Autores principales: Yang, Hai-Zhou, Gao, Hai-Tao, Yang, Xu-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967973/
https://www.ncbi.nlm.nih.gov/pubmed/21581700
http://dx.doi.org/10.1107/S1600536808040567
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author Yang, Hai-Zhou
Gao, Hai-Tao
Yang, Xu-Hong
author_facet Yang, Hai-Zhou
Gao, Hai-Tao
Yang, Xu-Hong
author_sort Yang, Hai-Zhou
collection PubMed
description In the title compound, C(34)H(20)Cl(2)N(4)O(4), the two quinazoline heterocyclic systems and the adjacent chloro­benzene rings are not coplanar, but oriented at dihedral angles of 66.66 (13) and 52.48 (12)°, respectively. The quinazoline ring systems are nearly planar, with dihedral angles between the planes of the two rings of 5.43 (16) and 3.40 (14)°, and are oriented at dihedral angles of 79.73 (13) and 83.52 (13)° with respect to the adjacent benzene ring between them. Inter­molecular C—H⋯O hydrogen bonds contribute to the stability of the structure. In addition, weak π–π stacking inter­actions [centroid-to-centroid distances = 3.872 (1) and 3.876 (1) Å] are observed in the crystal structure.
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spelling pubmed-29679732010-12-30 3,3′-Bis(4-chloro­phen­yl)-2,2′-(m-phenyl­enedi­oxy)diquinazolin-4(3H)-one Yang, Hai-Zhou Gao, Hai-Tao Yang, Xu-Hong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(34)H(20)Cl(2)N(4)O(4), the two quinazoline heterocyclic systems and the adjacent chloro­benzene rings are not coplanar, but oriented at dihedral angles of 66.66 (13) and 52.48 (12)°, respectively. The quinazoline ring systems are nearly planar, with dihedral angles between the planes of the two rings of 5.43 (16) and 3.40 (14)°, and are oriented at dihedral angles of 79.73 (13) and 83.52 (13)° with respect to the adjacent benzene ring between them. Inter­molecular C—H⋯O hydrogen bonds contribute to the stability of the structure. In addition, weak π–π stacking inter­actions [centroid-to-centroid distances = 3.872 (1) and 3.876 (1) Å] are observed in the crystal structure. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967973/ /pubmed/21581700 http://dx.doi.org/10.1107/S1600536808040567 Text en © Yang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yang, Hai-Zhou
Gao, Hai-Tao
Yang, Xu-Hong
3,3′-Bis(4-chloro­phen­yl)-2,2′-(m-phenyl­enedi­oxy)diquinazolin-4(3H)-one
title 3,3′-Bis(4-chloro­phen­yl)-2,2′-(m-phenyl­enedi­oxy)diquinazolin-4(3H)-one
title_full 3,3′-Bis(4-chloro­phen­yl)-2,2′-(m-phenyl­enedi­oxy)diquinazolin-4(3H)-one
title_fullStr 3,3′-Bis(4-chloro­phen­yl)-2,2′-(m-phenyl­enedi­oxy)diquinazolin-4(3H)-one
title_full_unstemmed 3,3′-Bis(4-chloro­phen­yl)-2,2′-(m-phenyl­enedi­oxy)diquinazolin-4(3H)-one
title_short 3,3′-Bis(4-chloro­phen­yl)-2,2′-(m-phenyl­enedi­oxy)diquinazolin-4(3H)-one
title_sort 3,3′-bis(4-chloro­phen­yl)-2,2′-(m-phenyl­enedi­oxy)diquinazolin-4(3h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967973/
https://www.ncbi.nlm.nih.gov/pubmed/21581700
http://dx.doi.org/10.1107/S1600536808040567
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AT gaohaitao 33bis4chlorophenyl22mphenylenedioxydiquinazolin43hone
AT yangxuhong 33bis4chlorophenyl22mphenylenedioxydiquinazolin43hone

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