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4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol
The crystal of the title Schiff base compound, C(19)H(20)Cl(2)N(2)O(2), contains of two crystallographically independent molecules with similar conformations. In each molecule, two intramolecular O—H⋯N bonds generate S(6) motifs. The N atoms are also in close proximity to two H atoms of the dimeth...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967979/ https://www.ncbi.nlm.nih.gov/pubmed/21581707 http://dx.doi.org/10.1107/S1600536808038014 |
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author | Yeap, Chin Sing Kargar, Hadi Kia, Reza Fun, Hoong-Kun |
author_facet | Yeap, Chin Sing Kargar, Hadi Kia, Reza Fun, Hoong-Kun |
author_sort | Yeap, Chin Sing |
collection | PubMed |
description | The crystal of the title Schiff base compound, C(19)H(20)Cl(2)N(2)O(2), contains of two crystallographically independent molecules with similar conformations. In each molecule, two intramolecular O—H⋯N bonds generate S(6) motifs. The N atoms are also in close proximity to two H atoms of the dimethylpropane groups, with H⋯N distances between 2.59 and 2.62 Å. The imine group is coplanar with the benzene ring. The dihedral angles between the benzene rings in the two independent molecules are 58.20 (12) and 47.95 (12)°. The structure displays short intermolecular Cl⋯Cl [3.3869 (11) Å] and Cl⋯O [3.175 (2)–3.204 (2) Å] interactions. The crystal structure is further stabilized by weak intermolecular C—H⋯O, C—H⋯π and π–π [centroid–centroid distances 3.6416 (13)–3.8705 (14) Å] interactions. |
format | Text |
id | pubmed-2967979 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29679792010-12-30 4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol Yeap, Chin Sing Kargar, Hadi Kia, Reza Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal of the title Schiff base compound, C(19)H(20)Cl(2)N(2)O(2), contains of two crystallographically independent molecules with similar conformations. In each molecule, two intramolecular O—H⋯N bonds generate S(6) motifs. The N atoms are also in close proximity to two H atoms of the dimethylpropane groups, with H⋯N distances between 2.59 and 2.62 Å. The imine group is coplanar with the benzene ring. The dihedral angles between the benzene rings in the two independent molecules are 58.20 (12) and 47.95 (12)°. The structure displays short intermolecular Cl⋯Cl [3.3869 (11) Å] and Cl⋯O [3.175 (2)–3.204 (2) Å] interactions. The crystal structure is further stabilized by weak intermolecular C—H⋯O, C—H⋯π and π–π [centroid–centroid distances 3.6416 (13)–3.8705 (14) Å] interactions. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967979/ /pubmed/21581707 http://dx.doi.org/10.1107/S1600536808038014 Text en © Yeap et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yeap, Chin Sing Kargar, Hadi Kia, Reza Fun, Hoong-Kun 4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title | 4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_full | 4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_fullStr | 4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_full_unstemmed | 4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_short | 4,4′-Dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_sort | 4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967979/ https://www.ncbi.nlm.nih.gov/pubmed/21581707 http://dx.doi.org/10.1107/S1600536808038014 |
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