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4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenol

The crystal of the title Schiff base compound, C(19)H(20)Cl(2)N(2)O(2), contains of two crystallographically independent mol­ecules with similar conformations. In each mol­ecule, two intramolecular O—H⋯N bonds generate S(6) motifs. The N atoms are also in close proximity to two H atoms of the dimeth...

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Detalles Bibliográficos
Autores principales: Yeap, Chin Sing, Kargar, Hadi, Kia, Reza, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967979/
https://www.ncbi.nlm.nih.gov/pubmed/21581707
http://dx.doi.org/10.1107/S1600536808038014
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author Yeap, Chin Sing
Kargar, Hadi
Kia, Reza
Fun, Hoong-Kun
author_facet Yeap, Chin Sing
Kargar, Hadi
Kia, Reza
Fun, Hoong-Kun
author_sort Yeap, Chin Sing
collection PubMed
description The crystal of the title Schiff base compound, C(19)H(20)Cl(2)N(2)O(2), contains of two crystallographically independent mol­ecules with similar conformations. In each mol­ecule, two intramolecular O—H⋯N bonds generate S(6) motifs. The N atoms are also in close proximity to two H atoms of the dimethyl­propane groups, with H⋯N distances between 2.59 and 2.62 Å. The imine group is coplanar with the benzene ring. The dihedral angles between the benzene rings in the two independent mol­ecules are 58.20 (12) and 47.95 (12)°. The structure displays short inter­molecular Cl⋯Cl [3.3869 (11) Å] and Cl⋯O [3.175 (2)–3.204 (2) Å] inter­actions. The crystal structure is further stabilized by weak inter­molecular C—H⋯O, C—H⋯π and π–π [centroid–centroid distances 3.6416 (13)–3.8705 (14) Å] inter­actions.
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spelling pubmed-29679792010-12-30 4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenol Yeap, Chin Sing Kargar, Hadi Kia, Reza Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal of the title Schiff base compound, C(19)H(20)Cl(2)N(2)O(2), contains of two crystallographically independent mol­ecules with similar conformations. In each mol­ecule, two intramolecular O—H⋯N bonds generate S(6) motifs. The N atoms are also in close proximity to two H atoms of the dimethyl­propane groups, with H⋯N distances between 2.59 and 2.62 Å. The imine group is coplanar with the benzene ring. The dihedral angles between the benzene rings in the two independent mol­ecules are 58.20 (12) and 47.95 (12)°. The structure displays short inter­molecular Cl⋯Cl [3.3869 (11) Å] and Cl⋯O [3.175 (2)–3.204 (2) Å] inter­actions. The crystal structure is further stabilized by weak inter­molecular C—H⋯O, C—H⋯π and π–π [centroid–centroid distances 3.6416 (13)–3.8705 (14) Å] inter­actions. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967979/ /pubmed/21581707 http://dx.doi.org/10.1107/S1600536808038014 Text en © Yeap et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yeap, Chin Sing
Kargar, Hadi
Kia, Reza
Fun, Hoong-Kun
4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenol
title 4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenol
title_full 4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenol
title_fullStr 4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenol
title_full_unstemmed 4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenol
title_short 4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenol
title_sort 4,4′-dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967979/
https://www.ncbi.nlm.nih.gov/pubmed/21581707
http://dx.doi.org/10.1107/S1600536808038014
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