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N (2),N (2′)-Bis(2-hydroxybenzylidene)-2,2′-bipyridyl-3,3′-dicarbohydrazide
In the title compound, C(26)H(20)N(6)O(4), the two aroylhydrazone side groups exist as diastereomeres, both in the keto form in the crystal structure. The aroylhydrazone units support the molecular conformation through an intramolecular N—H⋯O hydrogen bond. Two molecules are connected into a cent...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967985/ https://www.ncbi.nlm.nih.gov/pubmed/21581714 http://dx.doi.org/10.1107/S1600536808038087 |
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author | Miao, Shao-Bin Zang, Lu-Lu Fan, Ya-Wei Ji, Bao-Ming |
author_facet | Miao, Shao-Bin Zang, Lu-Lu Fan, Ya-Wei Ji, Bao-Ming |
author_sort | Miao, Shao-Bin |
collection | PubMed |
description | In the title compound, C(26)H(20)N(6)O(4), the two aroylhydrazone side groups exist as diastereomeres, both in the keto form in the crystal structure. The aroylhydrazone units support the molecular conformation through an intramolecular N—H⋯O hydrogen bond. Two molecules are connected into a centrosymmetric dimer by intermolecular N—H⋯N hydrogen bonds. These dimers are connected into chains along the a axis by intermolecular O—H⋯O hydrogen bonds. The combination of these hydrogen bonds results in layers in the bc plane. The layers are further linked by weak C—H⋯π contacts to form a three-dimensional network structure. |
format | Text |
id | pubmed-2967985 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29679852010-12-30 N (2),N (2′)-Bis(2-hydroxybenzylidene)-2,2′-bipyridyl-3,3′-dicarbohydrazide Miao, Shao-Bin Zang, Lu-Lu Fan, Ya-Wei Ji, Bao-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(20)N(6)O(4), the two aroylhydrazone side groups exist as diastereomeres, both in the keto form in the crystal structure. The aroylhydrazone units support the molecular conformation through an intramolecular N—H⋯O hydrogen bond. Two molecules are connected into a centrosymmetric dimer by intermolecular N—H⋯N hydrogen bonds. These dimers are connected into chains along the a axis by intermolecular O—H⋯O hydrogen bonds. The combination of these hydrogen bonds results in layers in the bc plane. The layers are further linked by weak C—H⋯π contacts to form a three-dimensional network structure. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967985/ /pubmed/21581714 http://dx.doi.org/10.1107/S1600536808038087 Text en © Miao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Miao, Shao-Bin Zang, Lu-Lu Fan, Ya-Wei Ji, Bao-Ming N (2),N (2′)-Bis(2-hydroxybenzylidene)-2,2′-bipyridyl-3,3′-dicarbohydrazide |
title |
N
(2),N
(2′)-Bis(2-hydroxybenzylidene)-2,2′-bipyridyl-3,3′-dicarbohydrazide |
title_full |
N
(2),N
(2′)-Bis(2-hydroxybenzylidene)-2,2′-bipyridyl-3,3′-dicarbohydrazide |
title_fullStr |
N
(2),N
(2′)-Bis(2-hydroxybenzylidene)-2,2′-bipyridyl-3,3′-dicarbohydrazide |
title_full_unstemmed |
N
(2),N
(2′)-Bis(2-hydroxybenzylidene)-2,2′-bipyridyl-3,3′-dicarbohydrazide |
title_short |
N
(2),N
(2′)-Bis(2-hydroxybenzylidene)-2,2′-bipyridyl-3,3′-dicarbohydrazide |
title_sort | n
(2),n
(2′)-bis(2-hydroxybenzylidene)-2,2′-bipyridyl-3,3′-dicarbohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967985/ https://www.ncbi.nlm.nih.gov/pubmed/21581714 http://dx.doi.org/10.1107/S1600536808038087 |
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