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N (2),N (2′)-Bis(2-hydroxy­benzyl­idene)-2,2′-bipyridyl-3,3′-dicarbohydrazide

In the title compound, C(26)H(20)N(6)O(4), the two aroylhydrazone side groups exist as diastereomeres, both in the keto form in the crystal structure. The aroylhydrazone units support the mol­ecular conformation through an intra­molecular N—H⋯O hydrogen bond. Two mol­ecules are connected into a cent...

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Detalles Bibliográficos
Autores principales: Miao, Shao-Bin, Zang, Lu-Lu, Fan, Ya-Wei, Ji, Bao-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967985/
https://www.ncbi.nlm.nih.gov/pubmed/21581714
http://dx.doi.org/10.1107/S1600536808038087
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author Miao, Shao-Bin
Zang, Lu-Lu
Fan, Ya-Wei
Ji, Bao-Ming
author_facet Miao, Shao-Bin
Zang, Lu-Lu
Fan, Ya-Wei
Ji, Bao-Ming
author_sort Miao, Shao-Bin
collection PubMed
description In the title compound, C(26)H(20)N(6)O(4), the two aroylhydrazone side groups exist as diastereomeres, both in the keto form in the crystal structure. The aroylhydrazone units support the mol­ecular conformation through an intra­molecular N—H⋯O hydrogen bond. Two mol­ecules are connected into a centrosymmetric dimer by inter­molecular N—H⋯N hydrogen bonds. These dimers are connected into chains along the a axis by inter­molecular O—H⋯O hydrogen bonds. The combination of these hydrogen bonds results in layers in the bc plane. The layers are further linked by weak C—H⋯π contacts to form a three-dimensional network structure.
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spelling pubmed-29679852010-12-30 N (2),N (2′)-Bis(2-hydroxy­benzyl­idene)-2,2′-bipyridyl-3,3′-dicarbohydrazide Miao, Shao-Bin Zang, Lu-Lu Fan, Ya-Wei Ji, Bao-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(20)N(6)O(4), the two aroylhydrazone side groups exist as diastereomeres, both in the keto form in the crystal structure. The aroylhydrazone units support the mol­ecular conformation through an intra­molecular N—H⋯O hydrogen bond. Two mol­ecules are connected into a centrosymmetric dimer by inter­molecular N—H⋯N hydrogen bonds. These dimers are connected into chains along the a axis by inter­molecular O—H⋯O hydrogen bonds. The combination of these hydrogen bonds results in layers in the bc plane. The layers are further linked by weak C—H⋯π contacts to form a three-dimensional network structure. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967985/ /pubmed/21581714 http://dx.doi.org/10.1107/S1600536808038087 Text en © Miao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Miao, Shao-Bin
Zang, Lu-Lu
Fan, Ya-Wei
Ji, Bao-Ming
N (2),N (2′)-Bis(2-hydroxy­benzyl­idene)-2,2′-bipyridyl-3,3′-dicarbohydrazide
title N (2),N (2′)-Bis(2-hydroxy­benzyl­idene)-2,2′-bipyridyl-3,3′-dicarbohydrazide
title_full N (2),N (2′)-Bis(2-hydroxy­benzyl­idene)-2,2′-bipyridyl-3,3′-dicarbohydrazide
title_fullStr N (2),N (2′)-Bis(2-hydroxy­benzyl­idene)-2,2′-bipyridyl-3,3′-dicarbohydrazide
title_full_unstemmed N (2),N (2′)-Bis(2-hydroxy­benzyl­idene)-2,2′-bipyridyl-3,3′-dicarbohydrazide
title_short N (2),N (2′)-Bis(2-hydroxy­benzyl­idene)-2,2′-bipyridyl-3,3′-dicarbohydrazide
title_sort n (2),n (2′)-bis(2-hydroxy­benzyl­idene)-2,2′-bipyridyl-3,3′-dicarbohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967985/
https://www.ncbi.nlm.nih.gov/pubmed/21581714
http://dx.doi.org/10.1107/S1600536808038087
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