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(E)-2-[4-(Dimethylamino)styryl]-1-methylquinolinium 4-methylbenzenesulfonate monohydrate
In the title compound, C(20)H(21)N(2) (+)·C(7)H(7)O(3)S(−)·H(2)O, the cation is essentially planar, as indicated by the dihedral angle of 2.79 (13)° between the quinolinium and the dimethylaminophenyl rings, and exists in the E configuration. The π-conjugated planes of the cation and the anion are i...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967986/ https://www.ncbi.nlm.nih.gov/pubmed/21581715 http://dx.doi.org/10.1107/S1600536808040671 |
Sumario: | In the title compound, C(20)H(21)N(2) (+)·C(7)H(7)O(3)S(−)·H(2)O, the cation is essentially planar, as indicated by the dihedral angle of 2.79 (13)° between the quinolinium and the dimethylaminophenyl rings, and exists in the E configuration. The π-conjugated planes of the cation and the anion are inclined to each other at a dihedral angle of 66.95 (12)°. The cation is linked to the anion through C—H⋯O hydrogen bonds and the anion is further linked with the water molecule by O—H⋯O hydrogen bonds, forming a three-molecule unit. These units are arranged in a face-to-face manner into a ribbon-like structure along the b axis. The ribbons are stacked along the c axis. The crystal structure is further stabilized by C—H⋯π interactions involving the dimethylaminophenyl and methylphenyl rings. A π–π interaction with a centroid–centroid distance of 3.6074 (19) Å is also observed. |
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