(Z)-Ethyl 3-(4-chloro­benzamido)-2-cyano-3-(4-fluoro­phen­yl)acrylate

The title compound, C(19)H(14)ClFN(2)O(3), was prepared by the reaction of ethyl (Z)-3-amino-2-cyano-3-(4-fluoro­phen­yl)acrylate and 4-chloro­benzoyl chloride. The dihedral angle between the chloro­benzene and fluoro­benzene rings is 66.18 (19)°. In addition to an intra­molecular N—H⋯O hydrogen bon...

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Detalles Bibliográficos
Autores principales: Zhang, Dehua, Zhang, Xiaoyan, Guo, Lijuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967997/
https://www.ncbi.nlm.nih.gov/pubmed/21581728
http://dx.doi.org/10.1107/S1600536808041469
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author Zhang, Dehua
Zhang, Xiaoyan
Guo, Lijuan
author_facet Zhang, Dehua
Zhang, Xiaoyan
Guo, Lijuan
author_sort Zhang, Dehua
collection PubMed
description The title compound, C(19)H(14)ClFN(2)O(3), was prepared by the reaction of ethyl (Z)-3-amino-2-cyano-3-(4-fluoro­phen­yl)acrylate and 4-chloro­benzoyl chloride. The dihedral angle between the chloro­benzene and fluoro­benzene rings is 66.18 (19)°. In addition to an intra­molecular N—H⋯O hydrogen bond, there are inter­molecular C—H⋯O and C—H⋯N hydrogen bonding inter­actions, which stabilize the crystal structure.
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spelling pubmed-29679972010-12-30 (Z)-Ethyl 3-(4-chloro­benzamido)-2-cyano-3-(4-fluoro­phen­yl)acrylate Zhang, Dehua Zhang, Xiaoyan Guo, Lijuan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(14)ClFN(2)O(3), was prepared by the reaction of ethyl (Z)-3-amino-2-cyano-3-(4-fluoro­phen­yl)acrylate and 4-chloro­benzoyl chloride. The dihedral angle between the chloro­benzene and fluoro­benzene rings is 66.18 (19)°. In addition to an intra­molecular N—H⋯O hydrogen bond, there are inter­molecular C—H⋯O and C—H⋯N hydrogen bonding inter­actions, which stabilize the crystal structure. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967997/ /pubmed/21581728 http://dx.doi.org/10.1107/S1600536808041469 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Dehua
Zhang, Xiaoyan
Guo, Lijuan
(Z)-Ethyl 3-(4-chloro­benzamido)-2-cyano-3-(4-fluoro­phen­yl)acrylate
title (Z)-Ethyl 3-(4-chloro­benzamido)-2-cyano-3-(4-fluoro­phen­yl)acrylate
title_full (Z)-Ethyl 3-(4-chloro­benzamido)-2-cyano-3-(4-fluoro­phen­yl)acrylate
title_fullStr (Z)-Ethyl 3-(4-chloro­benzamido)-2-cyano-3-(4-fluoro­phen­yl)acrylate
title_full_unstemmed (Z)-Ethyl 3-(4-chloro­benzamido)-2-cyano-3-(4-fluoro­phen­yl)acrylate
title_short (Z)-Ethyl 3-(4-chloro­benzamido)-2-cyano-3-(4-fluoro­phen­yl)acrylate
title_sort (z)-ethyl 3-(4-chloro­benzamido)-2-cyano-3-(4-fluoro­phen­yl)acrylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967997/
https://www.ncbi.nlm.nih.gov/pubmed/21581728
http://dx.doi.org/10.1107/S1600536808041469
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AT zhangxiaoyan zethyl34chlorobenzamido2cyano34fluorophenylacrylate
AT guolijuan zethyl34chlorobenzamido2cyano34fluorophenylacrylate

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