Ethyl 4-anilino-3-nitrobenzoate

In the title compound, C(15)H(14)N(2)O(4), the aromatic rings are oriented at a dihedral angle of 78.33 (3)°. An intra­molecular N—H⋯O hydrogen bond results in a non-planar six-membered ring with a flattened-boat conformation. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the m...

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Detalles Bibliográficos
Autores principales: Li, Hao-Yuan, Liu, Bo-Nian, Tang, Shi-Gui, Guo, Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967998/
https://www.ncbi.nlm.nih.gov/pubmed/21581729
http://dx.doi.org/10.1107/S1600536808041329
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author Li, Hao-Yuan
Liu, Bo-Nian
Tang, Shi-Gui
Guo, Cheng
author_facet Li, Hao-Yuan
Liu, Bo-Nian
Tang, Shi-Gui
Guo, Cheng
author_sort Li, Hao-Yuan
collection PubMed
description In the title compound, C(15)H(14)N(2)O(4), the aromatic rings are oriented at a dihedral angle of 78.33 (3)°. An intra­molecular N—H⋯O hydrogen bond results in a non-planar six-membered ring with a flattened-boat conformation. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules. π–π contacts between the phenyl rings and both the phenyl and benzene rings, [centroid–centroid distances = 3.841 (3) and 3.961 (3) Å] may further stabilize the structure.
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spelling pubmed-29679982010-12-30 Ethyl 4-anilino-3-nitrobenzoate Li, Hao-Yuan Liu, Bo-Nian Tang, Shi-Gui Guo, Cheng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(14)N(2)O(4), the aromatic rings are oriented at a dihedral angle of 78.33 (3)°. An intra­molecular N—H⋯O hydrogen bond results in a non-planar six-membered ring with a flattened-boat conformation. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules. π–π contacts between the phenyl rings and both the phenyl and benzene rings, [centroid–centroid distances = 3.841 (3) and 3.961 (3) Å] may further stabilize the structure. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967998/ /pubmed/21581729 http://dx.doi.org/10.1107/S1600536808041329 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Hao-Yuan
Liu, Bo-Nian
Tang, Shi-Gui
Guo, Cheng
Ethyl 4-anilino-3-nitrobenzoate
title Ethyl 4-anilino-3-nitrobenzoate
title_full Ethyl 4-anilino-3-nitrobenzoate
title_fullStr Ethyl 4-anilino-3-nitrobenzoate
title_full_unstemmed Ethyl 4-anilino-3-nitrobenzoate
title_short Ethyl 4-anilino-3-nitrobenzoate
title_sort ethyl 4-anilino-3-nitrobenzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967998/
https://www.ncbi.nlm.nih.gov/pubmed/21581729
http://dx.doi.org/10.1107/S1600536808041329
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AT liubonian ethyl4anilino3nitrobenzoate
AT tangshigui ethyl4anilino3nitrobenzoate
AT guocheng ethyl4anilino3nitrobenzoate

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