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{μ-N,N′-Bis[1-(2-pyridyl)ethylidene]benzene-1,2-diamine}di-μ-chlorido-bis[diaquanickel(II)] dichloride ethanol disolvate
In the title compound, [Ni(2)Cl(2)(C(20)H(18)N(4))(H(2)O)(4)]Cl(2)·2C(2)H(6)O, the coordination environment of each Ni(2+) ion is distorted octahedral formed by two N atoms from the Schiff base ligand, two O atoms from water molecules and two chloride anions acting as μ(2) bridges between the meta...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968006/ https://www.ncbi.nlm.nih.gov/pubmed/21581468 http://dx.doi.org/10.1107/S1600536808041299 |
Sumario: | In the title compound, [Ni(2)Cl(2)(C(20)H(18)N(4))(H(2)O)(4)]Cl(2)·2C(2)H(6)O, the coordination environment of each Ni(2+) ion is distorted octahedral formed by two N atoms from the Schiff base ligand, two O atoms from water molecules and two chloride anions acting as μ(2) bridges between the metal ions. The coordinated water molecules are linked to the uncoordinated ethanol molecules and chloride anions by O—H⋯O and O—H⋯Cl hydrogen bonds, although the assignment of some of these is tentative. A weak intermolecular O—H⋯N interaction within the ligand is also observed. |
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