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Diaqua(5-methylpyrazine-2-carboxylato-κ(2) N (1),O)iron(II)
In the neutral title complex, [Fe(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)], the coordination geometry aound the Fe(II) atom, which lies on an inversion centre, is distorted octahedral comprising two N atoms and two O atoms from two 5-methylpyrazine-2-carboxylate ligands, and two water molecules. The crys...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968011/ https://www.ncbi.nlm.nih.gov/pubmed/21581473 http://dx.doi.org/10.1107/S1600536808042529 |
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author | Fan, Guang Sun, Jia-Juan Zhang, Jun-Cai Ma, Zhan-Ying Gao, Sheng-Li |
author_facet | Fan, Guang Sun, Jia-Juan Zhang, Jun-Cai Ma, Zhan-Ying Gao, Sheng-Li |
author_sort | Fan, Guang |
collection | PubMed |
description | In the neutral title complex, [Fe(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)], the coordination geometry aound the Fe(II) atom, which lies on an inversion centre, is distorted octahedral comprising two N atoms and two O atoms from two 5-methylpyrazine-2-carboxylate ligands, and two water molecules. The crystal structure is stabilized by a network of O—H⋯O hydrogen bonds, resulting in a two-dimensional supramolecular structure. |
format | Text |
id | pubmed-2968011 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29680112010-12-30 Diaqua(5-methylpyrazine-2-carboxylato-κ(2) N (1),O)iron(II) Fan, Guang Sun, Jia-Juan Zhang, Jun-Cai Ma, Zhan-Ying Gao, Sheng-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the neutral title complex, [Fe(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)], the coordination geometry aound the Fe(II) atom, which lies on an inversion centre, is distorted octahedral comprising two N atoms and two O atoms from two 5-methylpyrazine-2-carboxylate ligands, and two water molecules. The crystal structure is stabilized by a network of O—H⋯O hydrogen bonds, resulting in a two-dimensional supramolecular structure. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968011/ /pubmed/21581473 http://dx.doi.org/10.1107/S1600536808042529 Text en © Fan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fan, Guang Sun, Jia-Juan Zhang, Jun-Cai Ma, Zhan-Ying Gao, Sheng-Li Diaqua(5-methylpyrazine-2-carboxylato-κ(2) N (1),O)iron(II) |
title | Diaqua(5-methylpyrazine-2-carboxylato-κ(2)
N
(1),O)iron(II) |
title_full | Diaqua(5-methylpyrazine-2-carboxylato-κ(2)
N
(1),O)iron(II) |
title_fullStr | Diaqua(5-methylpyrazine-2-carboxylato-κ(2)
N
(1),O)iron(II) |
title_full_unstemmed | Diaqua(5-methylpyrazine-2-carboxylato-κ(2)
N
(1),O)iron(II) |
title_short | Diaqua(5-methylpyrazine-2-carboxylato-κ(2)
N
(1),O)iron(II) |
title_sort | diaqua(5-methylpyrazine-2-carboxylato-κ(2)
n
(1),o)iron(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968011/ https://www.ncbi.nlm.nih.gov/pubmed/21581473 http://dx.doi.org/10.1107/S1600536808042529 |
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