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{μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)europium(III) methanol disolvate

The title dinuclear complex, [EuNi(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, is isostructural with its Ni(II)/Pr(III) analogue. The Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two methanol mol­ecules, forming a slightly distorted octa­hedral geo...

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Detalles Bibliográficos
Autor principal: Liu, Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968012/
https://www.ncbi.nlm.nih.gov/pubmed/21581474
http://dx.doi.org/10.1107/S1600536808041445
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author Liu, Fei
author_facet Liu, Fei
author_sort Liu, Fei
collection PubMed
description The title dinuclear complex, [EuNi(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, is isostructural with its Ni(II)/Pr(III) analogue. The Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two methanol mol­ecules, forming a slightly distorted octa­hedral geometry. The Eu(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from a Schiff base ligand, forming a distorted bicapped square-anti­prismatic environment. Inter­molecular O—H⋯O hydrogen bonds connect complexes and methanol solvent mol­ecules.
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spelling pubmed-29680122010-12-30 {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)europium(III) methanol disolvate Liu, Fei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear complex, [EuNi(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, is isostructural with its Ni(II)/Pr(III) analogue. The Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two methanol mol­ecules, forming a slightly distorted octa­hedral geometry. The Eu(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from a Schiff base ligand, forming a distorted bicapped square-anti­prismatic environment. Inter­molecular O—H⋯O hydrogen bonds connect complexes and methanol solvent mol­ecules. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968012/ /pubmed/21581474 http://dx.doi.org/10.1107/S1600536808041445 Text en © Fei Liu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Fei
{μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)europium(III) methanol disolvate
title {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)europium(III) methanol disolvate
title_full {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)europium(III) methanol disolvate
title_fullStr {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)europium(III) methanol disolvate
title_full_unstemmed {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)europium(III) methanol disolvate
title_short {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(II)europium(III) methanol disolvate
title_sort {μ-6,6′-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethano­ltrinitratonickel(ii)europium(iii) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968012/
https://www.ncbi.nlm.nih.gov/pubmed/21581474
http://dx.doi.org/10.1107/S1600536808041445
work_keys_str_mv AT liufei m66dimethoxy22propane13diylbisnitrilomethylidynediphenolatodimethanoltrinitratonickeliieuropiumiiimethanoldisolvate