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{μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)europium(III) methanol disolvate
The title dinuclear complex, [EuNi(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, is isostructural with its Ni(II)/Pr(III) analogue. The Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two methanol molecules, forming a slightly distorted octahedral geo...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968012/ https://www.ncbi.nlm.nih.gov/pubmed/21581474 http://dx.doi.org/10.1107/S1600536808041445 |
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author | Liu, Fei |
author_facet | Liu, Fei |
author_sort | Liu, Fei |
collection | PubMed |
description | The title dinuclear complex, [EuNi(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, is isostructural with its Ni(II)/Pr(III) analogue. The Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two methanol molecules, forming a slightly distorted octahedral geometry. The Eu(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from a Schiff base ligand, forming a distorted bicapped square-antiprismatic environment. Intermolecular O—H⋯O hydrogen bonds connect complexes and methanol solvent molecules. |
format | Text |
id | pubmed-2968012 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29680122010-12-30 {μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)europium(III) methanol disolvate Liu, Fei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear complex, [EuNi(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, is isostructural with its Ni(II)/Pr(III) analogue. The Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two methanol molecules, forming a slightly distorted octahedral geometry. The Eu(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from a Schiff base ligand, forming a distorted bicapped square-antiprismatic environment. Intermolecular O—H⋯O hydrogen bonds connect complexes and methanol solvent molecules. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968012/ /pubmed/21581474 http://dx.doi.org/10.1107/S1600536808041445 Text en © Fei Liu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Fei {μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)europium(III) methanol disolvate |
title | {μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)europium(III) methanol disolvate |
title_full | {μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)europium(III) methanol disolvate |
title_fullStr | {μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)europium(III) methanol disolvate |
title_full_unstemmed | {μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)europium(III) methanol disolvate |
title_short | {μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)europium(III) methanol disolvate |
title_sort | {μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(ii)europium(iii) methanol disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968012/ https://www.ncbi.nlm.nih.gov/pubmed/21581474 http://dx.doi.org/10.1107/S1600536808041445 |
work_keys_str_mv | AT liufei m66dimethoxy22propane13diylbisnitrilomethylidynediphenolatodimethanoltrinitratonickeliieuropiumiiimethanoldisolvate |