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Aqua­bis(dichloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)

In the title complex, [Cu(C(2)HCl(2)O(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion has a distorted square-pyramidal coordination geometry. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu—N = 1.994 (3) and 2.027 (3) Å] and two O atoms from dichloro­acetate...

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Detalles Bibliográficos
Autores principales: Liu, Yaru, Ning, Jianzhong, Sun, Junshan, Zhang, Chuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968015/
https://www.ncbi.nlm.nih.gov/pubmed/21581478
http://dx.doi.org/10.1107/S1600536808042578
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author Liu, Yaru
Ning, Jianzhong
Sun, Junshan
Zhang, Chuan
author_facet Liu, Yaru
Ning, Jianzhong
Sun, Junshan
Zhang, Chuan
author_sort Liu, Yaru
collection PubMed
description In the title complex, [Cu(C(2)HCl(2)O(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion has a distorted square-pyramidal coordination geometry. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu—N = 1.994 (3) and 2.027 (3) Å] and two O atoms from dichloro­acetate ligands and a water mol­ecule [Cu—O = 1.971 (2) and 1.939 (2) Å]. One O atom from another dichloro­acetate ligand occupies the apical positon [Cu—O = 2.152 (3) Å]. Inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers. The crystal packing also exhibits weak inter­molecular C—H⋯O hydrogen bonds, π–π inter­actions [centroid–centroid distance = 3.734 (2) Å] and short inter­molecular Cl⋯Cl contacts [3.306 (2) and 3.278 (2) Å].
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spelling pubmed-29680152010-12-30 Aqua­bis(dichloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) Liu, Yaru Ning, Jianzhong Sun, Junshan Zhang, Chuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(2)HCl(2)O(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion has a distorted square-pyramidal coordination geometry. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu—N = 1.994 (3) and 2.027 (3) Å] and two O atoms from dichloro­acetate ligands and a water mol­ecule [Cu—O = 1.971 (2) and 1.939 (2) Å]. One O atom from another dichloro­acetate ligand occupies the apical positon [Cu—O = 2.152 (3) Å]. Inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers. The crystal packing also exhibits weak inter­molecular C—H⋯O hydrogen bonds, π–π inter­actions [centroid–centroid distance = 3.734 (2) Å] and short inter­molecular Cl⋯Cl contacts [3.306 (2) and 3.278 (2) Å]. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968015/ /pubmed/21581478 http://dx.doi.org/10.1107/S1600536808042578 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Yaru
Ning, Jianzhong
Sun, Junshan
Zhang, Chuan
Aqua­bis(dichloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title Aqua­bis(dichloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full Aqua­bis(dichloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr Aqua­bis(dichloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed Aqua­bis(dichloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_short Aqua­bis(dichloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_sort aqua­bis(dichloro­acetato-κo)(1,10-phenanthroline-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968015/
https://www.ncbi.nlm.nih.gov/pubmed/21581478
http://dx.doi.org/10.1107/S1600536808042578
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