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Aquabis(dichloroacetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
In the title complex, [Cu(C(2)HCl(2)O(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion has a distorted square-pyramidal coordination geometry. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu—N = 1.994 (3) and 2.027 (3) Å] and two O atoms from dichloroacetate...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968015/ https://www.ncbi.nlm.nih.gov/pubmed/21581478 http://dx.doi.org/10.1107/S1600536808042578 |
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author | Liu, Yaru Ning, Jianzhong Sun, Junshan Zhang, Chuan |
author_facet | Liu, Yaru Ning, Jianzhong Sun, Junshan Zhang, Chuan |
author_sort | Liu, Yaru |
collection | PubMed |
description | In the title complex, [Cu(C(2)HCl(2)O(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion has a distorted square-pyramidal coordination geometry. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu—N = 1.994 (3) and 2.027 (3) Å] and two O atoms from dichloroacetate ligands and a water molecule [Cu—O = 1.971 (2) and 1.939 (2) Å]. One O atom from another dichloroacetate ligand occupies the apical positon [Cu—O = 2.152 (3) Å]. Intermolecular O—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. The crystal packing also exhibits weak intermolecular C—H⋯O hydrogen bonds, π–π interactions [centroid–centroid distance = 3.734 (2) Å] and short intermolecular Cl⋯Cl contacts [3.306 (2) and 3.278 (2) Å]. |
format | Text |
id | pubmed-2968015 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29680152010-12-30 Aquabis(dichloroacetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) Liu, Yaru Ning, Jianzhong Sun, Junshan Zhang, Chuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(2)HCl(2)O(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion has a distorted square-pyramidal coordination geometry. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu—N = 1.994 (3) and 2.027 (3) Å] and two O atoms from dichloroacetate ligands and a water molecule [Cu—O = 1.971 (2) and 1.939 (2) Å]. One O atom from another dichloroacetate ligand occupies the apical positon [Cu—O = 2.152 (3) Å]. Intermolecular O—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. The crystal packing also exhibits weak intermolecular C—H⋯O hydrogen bonds, π–π interactions [centroid–centroid distance = 3.734 (2) Å] and short intermolecular Cl⋯Cl contacts [3.306 (2) and 3.278 (2) Å]. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968015/ /pubmed/21581478 http://dx.doi.org/10.1107/S1600536808042578 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Yaru Ning, Jianzhong Sun, Junshan Zhang, Chuan Aquabis(dichloroacetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) |
title | Aquabis(dichloroacetato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full | Aquabis(dichloroacetato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_fullStr | Aquabis(dichloroacetato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full_unstemmed | Aquabis(dichloroacetato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_short | Aquabis(dichloroacetato-κO)(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_sort | aquabis(dichloroacetato-κo)(1,10-phenanthroline-κ(2)
n,n′)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968015/ https://www.ncbi.nlm.nih.gov/pubmed/21581478 http://dx.doi.org/10.1107/S1600536808042578 |
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