Triaqua­chlorido(1,10-phenanthroline-κ(2) N,N′)cobalt(II) chloride monohydrate

In the title compound, [CoCl(C(12)H(8)N(2))(H(2)O)(3)]Cl·H(2)O, the Co(II) ion is coordinated by two N atoms from the 1,10-phenanthroline ligand [Co—N = 2.125 (6) and 2.146 (6) Å], one chloride ligand [Co—Cl = 2.459 (2)Å] and three water mol­ecules [Co—O = 2.070 (5)–2.105 (5)Å] in a distorted octa­h...

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Detalles Bibliográficos
Autores principales: Liu, Yaru, Pan, Yutian, Sun, Junshan, Zhang, Chuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968016/
https://www.ncbi.nlm.nih.gov/pubmed/21581479
http://dx.doi.org/10.1107/S1600536808042591
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author Liu, Yaru
Pan, Yutian
Sun, Junshan
Zhang, Chuan
author_facet Liu, Yaru
Pan, Yutian
Sun, Junshan
Zhang, Chuan
author_sort Liu, Yaru
collection PubMed
description In the title compound, [CoCl(C(12)H(8)N(2))(H(2)O)(3)]Cl·H(2)O, the Co(II) ion is coordinated by two N atoms from the 1,10-phenanthroline ligand [Co—N = 2.125 (6) and 2.146 (6) Å], one chloride ligand [Co—Cl = 2.459 (2)Å] and three water mol­ecules [Co—O = 2.070 (5)–2.105 (5)Å] in a distorted octa­hedral geometry. Inter­molecular O—H⋯Cl and O—H⋯O hydrogen bonds form an extensive three-dimensional hydrogen-bonding network, which consolidates the crystal packing.
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spelling pubmed-29680162010-12-30 Triaqua­chlorido(1,10-phenanthroline-κ(2) N,N′)cobalt(II) chloride monohydrate Liu, Yaru Pan, Yutian Sun, Junshan Zhang, Chuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(C(12)H(8)N(2))(H(2)O)(3)]Cl·H(2)O, the Co(II) ion is coordinated by two N atoms from the 1,10-phenanthroline ligand [Co—N = 2.125 (6) and 2.146 (6) Å], one chloride ligand [Co—Cl = 2.459 (2)Å] and three water mol­ecules [Co—O = 2.070 (5)–2.105 (5)Å] in a distorted octa­hedral geometry. Inter­molecular O—H⋯Cl and O—H⋯O hydrogen bonds form an extensive three-dimensional hydrogen-bonding network, which consolidates the crystal packing. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968016/ /pubmed/21581479 http://dx.doi.org/10.1107/S1600536808042591 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Yaru
Pan, Yutian
Sun, Junshan
Zhang, Chuan
Triaqua­chlorido(1,10-phenanthroline-κ(2) N,N′)cobalt(II) chloride monohydrate
title Triaqua­chlorido(1,10-phenanthroline-κ(2) N,N′)cobalt(II) chloride monohydrate
title_full Triaqua­chlorido(1,10-phenanthroline-κ(2) N,N′)cobalt(II) chloride monohydrate
title_fullStr Triaqua­chlorido(1,10-phenanthroline-κ(2) N,N′)cobalt(II) chloride monohydrate
title_full_unstemmed Triaqua­chlorido(1,10-phenanthroline-κ(2) N,N′)cobalt(II) chloride monohydrate
title_short Triaqua­chlorido(1,10-phenanthroline-κ(2) N,N′)cobalt(II) chloride monohydrate
title_sort triaqua­chlorido(1,10-phenanthroline-κ(2) n,n′)cobalt(ii) chloride monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968016/
https://www.ncbi.nlm.nih.gov/pubmed/21581479
http://dx.doi.org/10.1107/S1600536808042591
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AT panyutian triaquachlorido110phenanthrolinek2nncobaltiichloridemonohydrate
AT sunjunshan triaquachlorido110phenanthrolinek2nncobaltiichloridemonohydrate
AT zhangchuan triaquachlorido110phenanthrolinek2nncobaltiichloridemonohydrate

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