catena-Poly[[4′,5′-bis­(methyl­sulfan­yl)-4,5-ethyl­enedithio­tetra­thio­fulvalene] [[dichloridomercurate(II)]-μ-dichlorido]]

The title compound, {(C(10)H(10)S(8))[HgCl(3)]}(n), is a sulfur-rich charge-transfer compound in which C(10)H(10)S(8) (+) cations and HgCl(3) anions are assembled by S⋯S [3.371 (5)–3.588 (5) Å] and S⋯Cl [2.833 (4)–3.488 (4) Å] contacts, and by weak inter­molecular C—H⋯Cl hydrogen bonds, forming a tw...

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Detalles Bibliográficos
Autores principales: Yang, Wei, Ren, Zhi-Gang, Dai, Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968017/
https://www.ncbi.nlm.nih.gov/pubmed/21581480
http://dx.doi.org/10.1107/S1600536808042785
Descripción
Sumario:The title compound, {(C(10)H(10)S(8))[HgCl(3)]}(n), is a sulfur-rich charge-transfer compound in which C(10)H(10)S(8) (+) cations and HgCl(3) anions are assembled by S⋯S [3.371 (5)–3.588 (5) Å] and S⋯Cl [2.833 (4)–3.488 (4) Å] contacts, and by weak inter­molecular C—H⋯Cl hydrogen bonds, forming a two-dimensional wave-like structure. The two C atoms of the –CH(2)—CH(2)– group in one of the cations are disordered over two sites with relative occupancies of 0.83 (2) and 0.17 (2).

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