catena-Poly[[4′,5′-bis­(methyl­sulfan­yl)-4,5-ethyl­enedithio­tetra­thio­fulvalene] [[dichloridomercurate(II)]-μ-dichlorido]]

The title compound, {(C(10)H(10)S(8))[HgCl(3)]}(n), is a sulfur-rich charge-transfer compound in which C(10)H(10)S(8) (+) cations and HgCl(3) anions are assembled by S⋯S [3.371 (5)–3.588 (5) Å] and S⋯Cl [2.833 (4)–3.488 (4) Å] contacts, and by weak inter­molecular C—H⋯Cl hydrogen bonds, forming a tw...

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Detalles Bibliográficos
Autores principales: Yang, Wei, Ren, Zhi-Gang, Dai, Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968017/
https://www.ncbi.nlm.nih.gov/pubmed/21581480
http://dx.doi.org/10.1107/S1600536808042785
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author Yang, Wei
Ren, Zhi-Gang
Dai, Jie
author_facet Yang, Wei
Ren, Zhi-Gang
Dai, Jie
author_sort Yang, Wei
collection PubMed
description The title compound, {(C(10)H(10)S(8))[HgCl(3)]}(n), is a sulfur-rich charge-transfer compound in which C(10)H(10)S(8) (+) cations and HgCl(3) anions are assembled by S⋯S [3.371 (5)–3.588 (5) Å] and S⋯Cl [2.833 (4)–3.488 (4) Å] contacts, and by weak inter­molecular C—H⋯Cl hydrogen bonds, forming a two-dimensional wave-like structure. The two C atoms of the –CH(2)—CH(2)– group in one of the cations are disordered over two sites with relative occupancies of 0.83 (2) and 0.17 (2).
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spelling pubmed-29680172010-12-30 catena-Poly[[4′,5′-bis­(methyl­sulfan­yl)-4,5-ethyl­enedithio­tetra­thio­fulvalene] [[dichloridomercurate(II)]-μ-dichlorido]] Yang, Wei Ren, Zhi-Gang Dai, Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {(C(10)H(10)S(8))[HgCl(3)]}(n), is a sulfur-rich charge-transfer compound in which C(10)H(10)S(8) (+) cations and HgCl(3) anions are assembled by S⋯S [3.371 (5)–3.588 (5) Å] and S⋯Cl [2.833 (4)–3.488 (4) Å] contacts, and by weak inter­molecular C—H⋯Cl hydrogen bonds, forming a two-dimensional wave-like structure. The two C atoms of the –CH(2)—CH(2)– group in one of the cations are disordered over two sites with relative occupancies of 0.83 (2) and 0.17 (2). International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968017/ /pubmed/21581480 http://dx.doi.org/10.1107/S1600536808042785 Text en © Yang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Wei
Ren, Zhi-Gang
Dai, Jie
catena-Poly[[4′,5′-bis­(methyl­sulfan­yl)-4,5-ethyl­enedithio­tetra­thio­fulvalene] [[dichloridomercurate(II)]-μ-dichlorido]]
title catena-Poly[[4′,5′-bis­(methyl­sulfan­yl)-4,5-ethyl­enedithio­tetra­thio­fulvalene] [[dichloridomercurate(II)]-μ-dichlorido]]
title_full catena-Poly[[4′,5′-bis­(methyl­sulfan­yl)-4,5-ethyl­enedithio­tetra­thio­fulvalene] [[dichloridomercurate(II)]-μ-dichlorido]]
title_fullStr catena-Poly[[4′,5′-bis­(methyl­sulfan­yl)-4,5-ethyl­enedithio­tetra­thio­fulvalene] [[dichloridomercurate(II)]-μ-dichlorido]]
title_full_unstemmed catena-Poly[[4′,5′-bis­(methyl­sulfan­yl)-4,5-ethyl­enedithio­tetra­thio­fulvalene] [[dichloridomercurate(II)]-μ-dichlorido]]
title_short catena-Poly[[4′,5′-bis­(methyl­sulfan­yl)-4,5-ethyl­enedithio­tetra­thio­fulvalene] [[dichloridomercurate(II)]-μ-dichlorido]]
title_sort catena-poly[[4′,5′-bis­(methyl­sulfan­yl)-4,5-ethyl­enedithio­tetra­thio­fulvalene] [[dichloridomercurate(ii)]-μ-dichlorido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968017/
https://www.ncbi.nlm.nih.gov/pubmed/21581480
http://dx.doi.org/10.1107/S1600536808042785
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AT renzhigang catenapoly45bismethylsulfanyl45ethylenedithiotetrathiofulvalenedichloridomercurateiimdichlorido
AT daijie catenapoly45bismethylsulfanyl45ethylenedithiotetrathiofulvalenedichloridomercurateiimdichlorido

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