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Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)]

In the crystal structure of the title complex, [Tb(C(6)H(4)NO(2))(C(2)O(4))(H(2)O)(2)](n), the Tb(III) ion is coordinated by two O atoms from two isonicotinate (inic) anions, four O atoms of two oxalate anions, and two water mol­ecules, displaying a distorted square-antiprismatic geometry. The Tb(II...

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Detalles Bibliográficos
Autores principales: Fang, Zhan-Qiang, Zeng, Rong-Hua, Li, Yan-Ting, Yang, Shuo, Song, Zhao-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968019/
https://www.ncbi.nlm.nih.gov/pubmed/21581482
http://dx.doi.org/10.1107/S1600536808042682
Descripción
Sumario:In the crystal structure of the title complex, [Tb(C(6)H(4)NO(2))(C(2)O(4))(H(2)O)(2)](n), the Tb(III) ion is coordinated by two O atoms from two isonicotinate (inic) anions, four O atoms of two oxalate anions, and two water mol­ecules, displaying a distorted square-antiprismatic geometry. The Tb(III) ion, the inic anion and the water mol­ecules occupy general positions. One of the two crystallographically independent oxalate anions is located on a center of inversion, whereas the second is located on the twofold rotation axis. The carboxyl­ate groups of the inic and oxalate anions link the terbium metal centres into layers. These layers are connected by O—H⋯O and N—H⋯O hydrogen bonding into a three-dimensional network.