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Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)]

In the crystal structure of the title complex, [Tb(C(6)H(4)NO(2))(C(2)O(4))(H(2)O)(2)](n), the Tb(III) ion is coordinated by two O atoms from two isonicotinate (inic) anions, four O atoms of two oxalate anions, and two water mol­ecules, displaying a distorted square-antiprismatic geometry. The Tb(II...

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Autores principales: Fang, Zhan-Qiang, Zeng, Rong-Hua, Li, Yan-Ting, Yang, Shuo, Song, Zhao-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968019/
https://www.ncbi.nlm.nih.gov/pubmed/21581482
http://dx.doi.org/10.1107/S1600536808042682
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author Fang, Zhan-Qiang
Zeng, Rong-Hua
Li, Yan-Ting
Yang, Shuo
Song, Zhao-Feng
author_facet Fang, Zhan-Qiang
Zeng, Rong-Hua
Li, Yan-Ting
Yang, Shuo
Song, Zhao-Feng
author_sort Fang, Zhan-Qiang
collection PubMed
description In the crystal structure of the title complex, [Tb(C(6)H(4)NO(2))(C(2)O(4))(H(2)O)(2)](n), the Tb(III) ion is coordinated by two O atoms from two isonicotinate (inic) anions, four O atoms of two oxalate anions, and two water mol­ecules, displaying a distorted square-antiprismatic geometry. The Tb(III) ion, the inic anion and the water mol­ecules occupy general positions. One of the two crystallographically independent oxalate anions is located on a center of inversion, whereas the second is located on the twofold rotation axis. The carboxyl­ate groups of the inic and oxalate anions link the terbium metal centres into layers. These layers are connected by O—H⋯O and N—H⋯O hydrogen bonding into a three-dimensional network.
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spelling pubmed-29680192010-12-30 Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)] Fang, Zhan-Qiang Zeng, Rong-Hua Li, Yan-Ting Yang, Shuo Song, Zhao-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [Tb(C(6)H(4)NO(2))(C(2)O(4))(H(2)O)(2)](n), the Tb(III) ion is coordinated by two O atoms from two isonicotinate (inic) anions, four O atoms of two oxalate anions, and two water mol­ecules, displaying a distorted square-antiprismatic geometry. The Tb(III) ion, the inic anion and the water mol­ecules occupy general positions. One of the two crystallographically independent oxalate anions is located on a center of inversion, whereas the second is located on the twofold rotation axis. The carboxyl­ate groups of the inic and oxalate anions link the terbium metal centres into layers. These layers are connected by O—H⋯O and N—H⋯O hydrogen bonding into a three-dimensional network. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968019/ /pubmed/21581482 http://dx.doi.org/10.1107/S1600536808042682 Text en © Fang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fang, Zhan-Qiang
Zeng, Rong-Hua
Li, Yan-Ting
Yang, Shuo
Song, Zhao-Feng
Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)]
title Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)]
title_full Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)]
title_fullStr Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)]
title_full_unstemmed Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)]
title_short Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)]
title_sort poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968019/
https://www.ncbi.nlm.nih.gov/pubmed/21581482
http://dx.doi.org/10.1107/S1600536808042682
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