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Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)]
In the crystal structure of the title complex, [Tb(C(6)H(4)NO(2))(C(2)O(4))(H(2)O)(2)](n), the Tb(III) ion is coordinated by two O atoms from two isonicotinate (inic) anions, four O atoms of two oxalate anions, and two water molecules, displaying a distorted square-antiprismatic geometry. The Tb(II...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968019/ https://www.ncbi.nlm.nih.gov/pubmed/21581482 http://dx.doi.org/10.1107/S1600536808042682 |
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author | Fang, Zhan-Qiang Zeng, Rong-Hua Li, Yan-Ting Yang, Shuo Song, Zhao-Feng |
author_facet | Fang, Zhan-Qiang Zeng, Rong-Hua Li, Yan-Ting Yang, Shuo Song, Zhao-Feng |
author_sort | Fang, Zhan-Qiang |
collection | PubMed |
description | In the crystal structure of the title complex, [Tb(C(6)H(4)NO(2))(C(2)O(4))(H(2)O)(2)](n), the Tb(III) ion is coordinated by two O atoms from two isonicotinate (inic) anions, four O atoms of two oxalate anions, and two water molecules, displaying a distorted square-antiprismatic geometry. The Tb(III) ion, the inic anion and the water molecules occupy general positions. One of the two crystallographically independent oxalate anions is located on a center of inversion, whereas the second is located on the twofold rotation axis. The carboxylate groups of the inic and oxalate anions link the terbium metal centres into layers. These layers are connected by O—H⋯O and N—H⋯O hydrogen bonding into a three-dimensional network. |
format | Text |
id | pubmed-2968019 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29680192010-12-30 Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)] Fang, Zhan-Qiang Zeng, Rong-Hua Li, Yan-Ting Yang, Shuo Song, Zhao-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [Tb(C(6)H(4)NO(2))(C(2)O(4))(H(2)O)(2)](n), the Tb(III) ion is coordinated by two O atoms from two isonicotinate (inic) anions, four O atoms of two oxalate anions, and two water molecules, displaying a distorted square-antiprismatic geometry. The Tb(III) ion, the inic anion and the water molecules occupy general positions. One of the two crystallographically independent oxalate anions is located on a center of inversion, whereas the second is located on the twofold rotation axis. The carboxylate groups of the inic and oxalate anions link the terbium metal centres into layers. These layers are connected by O—H⋯O and N—H⋯O hydrogen bonding into a three-dimensional network. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968019/ /pubmed/21581482 http://dx.doi.org/10.1107/S1600536808042682 Text en © Fang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fang, Zhan-Qiang Zeng, Rong-Hua Li, Yan-Ting Yang, Shuo Song, Zhao-Feng Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)] |
title | Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)] |
title_full | Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)] |
title_fullStr | Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)] |
title_full_unstemmed | Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)] |
title_short | Poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(III)] |
title_sort | poly[diaqua-μ(2)-isonicotinato-μ(2)-oxalato-terbium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968019/ https://www.ncbi.nlm.nih.gov/pubmed/21581482 http://dx.doi.org/10.1107/S1600536808042682 |
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