Poly[(μ-4,4′-bipyridine)(μ-naph­tha­lene-1,4-dicarboxyl­ato)iron(II)]

The asymmetric unit of the title compound, [Fe(C(12)H(6)O(4))(C(10)H(8)N(2))], consists of two independent Fe(II) atoms, two naphthalene-1,4-dicarboxyl­ate anions and two 4,4′-bipyridine ligands. The Fe(II) atoms are each coordinated by four O atoms of the naphthalene-1,4-dicarboxyl­ate anions and t...

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Detalles Bibliográficos
Autores principales: Boeckmann, Jan, Jess, Inke, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968022/
https://www.ncbi.nlm.nih.gov/pubmed/21581486
http://dx.doi.org/10.1107/S1600536808042992
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author Boeckmann, Jan
Jess, Inke
Näther, Christian
author_facet Boeckmann, Jan
Jess, Inke
Näther, Christian
author_sort Boeckmann, Jan
collection PubMed
description The asymmetric unit of the title compound, [Fe(C(12)H(6)O(4))(C(10)H(8)N(2))], consists of two independent Fe(II) atoms, two naphthalene-1,4-dicarboxyl­ate anions and two 4,4′-bipyridine ligands. The Fe(II) atoms are each coordinated by four O atoms of the naphthalene-1,4-dicarboxyl­ate anions and two N atoms of the 4,4′-bipyridine ligands within a distorted octa­hedron. Two Fe(II) atoms are bridged via the carboxyl­ate groups of two symmetry-related anions into dimers, which are further connected into chains. These chains are linked by additional anions into layers that are finally connected by the 4,4′-bipyridine ligands into a three-dimensional coordination network.
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spelling pubmed-29680222010-12-30 Poly[(μ-4,4′-bipyridine)(μ-naph­tha­lene-1,4-dicarboxyl­ato)iron(II)] Boeckmann, Jan Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Fe(C(12)H(6)O(4))(C(10)H(8)N(2))], consists of two independent Fe(II) atoms, two naphthalene-1,4-dicarboxyl­ate anions and two 4,4′-bipyridine ligands. The Fe(II) atoms are each coordinated by four O atoms of the naphthalene-1,4-dicarboxyl­ate anions and two N atoms of the 4,4′-bipyridine ligands within a distorted octa­hedron. Two Fe(II) atoms are bridged via the carboxyl­ate groups of two symmetry-related anions into dimers, which are further connected into chains. These chains are linked by additional anions into layers that are finally connected by the 4,4′-bipyridine ligands into a three-dimensional coordination network. International Union of Crystallography 2008-12-20 /pmc/articles/PMC2968022/ /pubmed/21581486 http://dx.doi.org/10.1107/S1600536808042992 Text en © Boeckmann et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boeckmann, Jan
Jess, Inke
Näther, Christian
Poly[(μ-4,4′-bipyridine)(μ-naph­tha­lene-1,4-dicarboxyl­ato)iron(II)]
title Poly[(μ-4,4′-bipyridine)(μ-naph­tha­lene-1,4-dicarboxyl­ato)iron(II)]
title_full Poly[(μ-4,4′-bipyridine)(μ-naph­tha­lene-1,4-dicarboxyl­ato)iron(II)]
title_fullStr Poly[(μ-4,4′-bipyridine)(μ-naph­tha­lene-1,4-dicarboxyl­ato)iron(II)]
title_full_unstemmed Poly[(μ-4,4′-bipyridine)(μ-naph­tha­lene-1,4-dicarboxyl­ato)iron(II)]
title_short Poly[(μ-4,4′-bipyridine)(μ-naph­tha­lene-1,4-dicarboxyl­ato)iron(II)]
title_sort poly[(μ-4,4′-bipyridine)(μ-naph­tha­lene-1,4-dicarboxyl­ato)iron(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968022/
https://www.ncbi.nlm.nih.gov/pubmed/21581486
http://dx.doi.org/10.1107/S1600536808042992
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